(1S,7S)-3β-Formyl-8,8-dimethyl-α,4-bis(methylene)bicyclo[5.1.0]octane-2β-acetaldehyde

Base Information

Chemical Name:(1S,7S)-3β-Formyl-8,8-dimethyl-α,4-bis(methylene)bicyclo[5.1.0]octane-2β-acetaldehyde
CAS No.:73407-82-6
Molecular Formula:C₁₅H₂₀O₂
Molecular Weight:232.323
Hs Code.:
Mol file:73407-82-6.mol

Synonyms:(-)-hangeokedial;(1S,2R,3R,7S)-2-(1-Formyl-vinyl)-8,8-dimethyl-4-methylene-bicyclo[5.1.0]octane-3-carbaldehyde;(-)-hanegokedial;plagiochilal A;

Suppliers and Price of (1S,7S)-3β-Formyl-8,8-dimethyl-α,4-bis(methylene)bicyclo[5.1.0]octane-2β-acetaldehyde

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (1S,7S)-3β-Formyl-8,8-dimethyl-α,4-bis(methylene)bicyclo[5.1.0]octane-2β-acetaldehyde

Chemical Property:

PSA：34.14000
LogP:2.79500

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of (1S,7S)-3β-Formyl-8,8-dimethyl-α,4-bis(methylene)bicyclo[5.1.0]octane-2β-acetaldehyde

There total 9 articles about (1S,7S)-3β-Formyl-8,8-dimethyl-α,4-bis(methylene)bicyclo[5.1.0]octane-2β-acetaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 87859-66-3
(1S,2R,3R,7S)-2-(1-Diethoxymethyl-vinyl)-8,8-dimethyl-4-methylene-bicyclo[5.1.0]octane-3-carbaldehyde

: 73407-82-6
(+)-hanegokedial

Guidance literature:: DOI:10.1016/S0040-4039(00)81792-X

Reference yield: 62.0%

: 182803-88-9
(1aS,4aR,5R,6S,7aR,7bS)-1,1-Dimethyl-4,7-dimethylene-decahydro-cyclopropa[e]azulene-5,6-diol

: 73407-82-6
(+)-hanegokedial

Guidance literature:: With potassium metaperiodate; In diethyl ether; water; at 0 ℃; for 32h;
DOI:10.1016/0031-9422(96)00257-9

Reference yield:

: Acetic acid (1aS,4aR,5R,6R,7S,7aR,7bS)-5-acetoxy-7-hydroxy-1,1,7-trimethyl-4-methylene-decahydro-cyclopropa[e]azulen-6-yl ester

: 73407-82-6
(+)-hanegokedial

Guidance literature:: Multi-step reaction with 3 steps

1: POCl₃ / pyridine / 72 h / Ambient temperature

2: 0.3 mg / Cs₂CO₃ / methanol; H₂O / 3 h

3: 62 percent / KIO₄ / diethyl ether; H₂O / 32 h / 0 °C

With potassium metaperiodate; caesium carbonate; trichlorophosphate; In pyridine; methanol; diethyl ether; water;
DOI:10.1016/0031-9422(96)00257-9