Plagiochiline C

Base Information

• Chemical Name: Plagiochiline C
• CAS No.: 73100-51-3
• Molecular Formula: C₁₉H₂₆O₅
• Molecular Weight: 334.412
• Mol file: 73100-51-3.mol

Synonyms:Acetic acid (1aS,4aR,5R,8aR,8bS)-8-acetoxymethyl-1,1-dimethyl-4-methylene-1a,2,3,4,4a,5,8a,8b-octahydro-1H-6-oxa-benzo[a]cyclopropa[c]cyclohepten-5-yl ester;plagiochiline C;

Chemical Property of Plagiochiline C

Chemical Property:

• PSA: 61.83000
• LogP: 3.20740

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Plagiochiline C

There total 2 articles about Plagiochiline C which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

plagiochiline L → (+)-ovalifoliene (73100-51-3)

Guidance literature:

Multi-step reaction with 2 steps

1: (COCl)2, NaNH₄ / dimethylformamide / 2 h / -20 °C

2: pyridine / 4 h

With pyridine; oxalyl dichloride; In N,N-dimethyl-formamide;

DOI:10.1016/0031-9422(94)00570-J

Reference yield:

acetic anhydride (108-24-7) + 4-O-deacetylplagiochiline C → (+)-ovalifoliene (73100-51-3)

Guidance literature:

With pyridine; for 4h; Yield given;

DOI:10.1016/0031-9422(94)00570-J

Reference yield:

(+)-ovalifoliene (73100-51-3) → ent-2β,14-diacetoxy-2,3-epoxy-10β-hydroxy-2,3-secoalloaromadendr-3-en-5-yl m-chlorobenzoate (80445-93-8) + ent-2β,14-diacetoxy-2,3:10β,15β-diepoxy-2,3-secoalloaromadendr-3-ene (73465-51-7)

Guidance literature:

With disodium hydrogenphosphate; 3-chloro-benzenecarboperoxoic acid; In chloroform; at 2 - 10 ℃; for 13h;

DOI:10.1039/P19810002816

upstream raw materials:

acetic anhydride

Downstream raw materials:

(+)-hanegokedial

ent-2β,14-diacetoxy-2,3-epoxy-10β-hydroxy-2,3-secoalloaromadendr-3-en-5-yl m-chlorobenzoate

ent-2β,14-diacetoxy-2,3:10β,15β-diepoxy-2,3-secoalloaromadendr-3-ene