Dimethyl acenaphthylene-5,6-dicarboxylate

Base Information

Chemical Name:Dimethyl acenaphthylene-5,6-dicarboxylate
CAS No.:92964-95-9
Molecular Formula:C16H12O4
Molecular Weight:268.2641
Hs Code.:
NSC Number:109922
DSSTox Substance ID:DTXSID00918813
Wikidata:Q82891108

Synonyms:dimethyl acenaphthylene-5,6-dicarboxylate;92964-95-9;NSC109922;DTXSID00918813;NSC-109922;SR-01000027748;SR-01000027748-1

Suppliers and Price of Dimethyl acenaphthylene-5,6-dicarboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 5 raw suppliers

Chemical Property of Dimethyl acenaphthylene-5,6-dicarboxylate

Chemical Property:

Vapor Pressure:5.81E-08mmHg at 25°C
Boiling Point:440.6°C at 760 mmHg
Flash Point:227.6°C
Density:1.315g/cm³
XLogP3:3.4
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:4
Exact Mass:268.07355886
Heavy Atom Count:20
Complexity:404

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC(=O)C1=C2C(=CC=C3C2=C(C=C3)C=C1)C(=O)OC

Technology Process of Dimethyl acenaphthylene-5,6-dicarboxylate

There total 3 articles about Dimethyl acenaphthylene-5,6-dicarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 92873-11-5
dimethyl 1-bromoacenaphthene-4,5-dicarboxylate

: 92964-95-9
dimethyl acenaphthylene-4,5-dicarboxylate

Guidance literature:: With lithium bromide; In N,N-dimethyl-formamide; at 115 ℃; for 2h;
DOI:10.1002/ejoc.200800954

Reference yield:

: 4599-96-6
Acenaphthen-5,6-dicarbonsaeure-dimethylester

: 92964-95-9
dimethyl acenaphthylene-4,5-dicarboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: NBS, (PhCO)2O₂ / CCl₄ / Heating

2: LiBr / dimethylformamide

With N-Bromosuccinimide; lithium bromide; dibenzoyl peroxide; In tetrachloromethane; N,N-dimethyl-formamide;
DOI:10.1021/jo01033a004

Reference yield:

: 5699-00-3
1,2-dihydro-6-oxacyclopentaphenalene-5,7-dione

: 92964-95-9
dimethyl acenaphthylene-4,5-dicarboxylate

Guidance literature:: Multi-step reaction with 3 steps

1: (i) aq. NaOH, (ii) /BRN= 635994/, aq. Na₂CO₃

2: NBS, (PhCO)2O₂ / CCl₄ / Heating

3: LiBr / dimethylformamide

With N-Bromosuccinimide; lithium bromide; dibenzoyl peroxide; In tetrachloromethane; N,N-dimethyl-formamide;
DOI:10.1021/jo01033a004