Acenaphthene, 5,6-bis(bromomethyl)-

Base Information

Chemical Name:Acenaphthene, 5,6-bis(bromomethyl)-
CAS No.:4599-95-5
Molecular Formula:C₁₄H₁₂Br₂
Molecular Weight:340.057
Hs Code.:
NSC Number:109953
DSSTox Substance ID:DTXSID90296576
Wikidata:Q82037237
Mol file:4599-95-5.mol

Synonyms:4599-95-5;Acenaphthene, 5,6-bis(bromomethyl)-;NSC109953;Acenaphthene,6-bis(bromomethyl)-;DTXSID90296576;NSC-109953

Suppliers and Price of Acenaphthene, 5,6-bis(bromomethyl)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 5 raw suppliers

Chemical Property of Acenaphthene, 5,6-bis(bromomethyl)-

Chemical Property:

Vapor Pressure:1.17E-07mmHg at 25°C
Boiling Point:443.9°C at 760 mmHg
Flash Point:259.7°C
Density:1.753g/cm³
XLogP3:4.6
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:2
Exact Mass:339.92853
Heavy Atom Count:16
Complexity:229

Purity/Quality:: 95% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1CC2=CC=C(C3=C(C=CC1=C23)CBr)CBr

Technology Process of Acenaphthene, 5,6-bis(bromomethyl)-

There total 8 articles about Acenaphthene, 5,6-bis(bromomethyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 4599-97-7
5,6-bis(hydroxymethyl)acenaphthene

: 4599-95-5
5,6-bis(bromomethyl)acenaphthene

Guidance literature:: With phosphorus tribromide;
DOI:10.1002/chem.200304824

Reference yield:

: 92873-11-5
dimethyl 1-bromoacenaphthene-4,5-dicarboxylate

: 4599-95-5
5,6-bis(bromomethyl)acenaphthene

Guidance literature:: Multi-step reaction with 4 steps

1: LiBr / dimethylformamide

2: H₂ / Pd-C / dioxane

3: LiAlH₄ / tetrahydrofuran

4: aq. HBr / dioxane

With lithium aluminium tetrahydride; hydrogen bromide; hydrogen; lithium bromide; palladium on activated charcoal; In tetrahydrofuran; 1,4-dioxane; N,N-dimethyl-formamide;
DOI:10.1021/jo01033a004

Reference yield:

: 92964-95-9
dimethyl acenaphthylene-4,5-dicarboxylate

: 4599-95-5
5,6-bis(bromomethyl)acenaphthene

Guidance literature:: Multi-step reaction with 3 steps

1: H₂ / Pd-C / dioxane

2: LiAlH₄ / tetrahydrofuran

3: aq. HBr / dioxane

With lithium aluminium tetrahydride; hydrogen bromide; hydrogen; palladium on activated charcoal; In tetrahydrofuran; 1,4-dioxane;
DOI:10.1021/jo01033a004