Sulfone, bis(p-azidophenyl)

Base Information

• Chemical Name: Sulfone, bis(p-azidophenyl)
• CAS No.: 7300-27-8
• Molecular Formula: C12H8N6O2S
• Molecular Weight: 300.301
• DSSTox Substance ID: DTXSID10223283
• Nikkaji Number: J781.096B
• Wikidata: Q83101720
• Mol file: 7300-27-8.mol

Synonyms:7300-27-8;Sulfone, bis(p-azidophenyl);4-Azidophenyl sulfone;p-Azidophenyl sulfone;1-azido-4-(4-azidophenyl)sulfonylbenzene;4,4'-Diazidodiphenylsulfone;4,4'-diazidodiphenyl sulfone;4,4'-Bis-triazodiphenylsulfone;Benzene, 1,1'-sulfonylbis(4-azido-;4,4'-sulfonylbis(azidobenzene);Bis(p-azidophenyl)sulfone;Bis(4-azidophenyl) sulfone;4,4'-Diazido-diphenylsulfone;4,4'-Diazino-diphenylsulfone;SCHEMBL13887514;DTXSID10223283;1,1'-sulfonylbis(4-azidobenzene);MFCD00043696;STK367742;AKOS005444944;1-azido-4-(4-azidophenyl)sulfonyl-benzene;LS-147961;FT-0617631

Chemical Property of Sulfone, bis(p-azidophenyl)

Chemical Property:

• PSA: 142.02000
• LogP: 4.38932
• XLogP3: 4.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 4
• Exact Mass: 300.04294469
• Heavy Atom Count: 21
• Complexity: 499

Purity/Quality:

99% ^*data from raw suppliers

4-Azidophenyl sulfone ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC(=CC=C1N=[N+]=[N-])S(=O)(=O)C2=CC=C(C=C2)N=[N+]=[N-]

Technology Process of Sulfone, bis(p-azidophenyl)

There total 1 articles about Sulfone, bis(p-azidophenyl) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

dapsone (80-08-0) → bis-(4-azido-phenyl)-sulfone (7300-27-8)

Guidance literature:

dapsone; With 1-methyl-2-oxopyrrolidinium hydrogen sulfate; In water; at 20 ℃; for 0.0166667h; Grinding;

With sodium nitrite; In water; at 20 ℃; Grinding;

With sodium azide; In water; at 20 ℃; Grinding;

DOI:10.1080/00304948.2011.613695

Reference yield: 95.0%

bis-(4-azido-phenyl)-sulfone (7300-27-8) → dapsone (80-08-0)

Guidance literature:

With methanol; sodium sulfide; for 0.0833333h;

DOI:10.1080/10426500490466544

Reference yield: 95.0%

bis-(4-azido-phenyl)-sulfone (7300-27-8) + acetylacetone (123-54-6,81235-32-7) → 1,1′‐((sulfonylbis(4,1‐phenylene))bis(5‐methyl‐1H‐1,2,3‐triazole‐1,4‐diyl))bis(ethan‐1‐one)

Guidance literature:

With sodium methylate; In ethanol; for 5h; Reflux;

DOI:10.3390/molecules26164817

upstream raw materials:

dapsone

Downstream raw materials:

5,5'-diamino-1H,1'H-1,1'-(4,4'-sulfonyl-diphenyl)-bis-[1,2,3]triazole-4-carboxylic acid diethyl ester

dapsone

C₄₂H₆₄N₁₄O₁₄S