Bromodiphenylphosphine 96%

Base Information

• Chemical Name: Bromodiphenylphosphine 96%
• CAS No.: 1079-65-8
• Molecular Formula: C12H10 Br P
• Molecular Weight: 265.089
• Hs Code.: 2903999090
• Mol file: 1079-65-8.mol

Synonyms:Phosphinousbromide, diphenyl- (6CI,7CI,8CI,9CI); Bromodiphenylphosphine;Diphenylbromophosphine; Diphenylphosphine bromide; Diphenylphosphinous bromide;NSC 203063

Chemical Property of Bromodiphenylphosphine 96%

Chemical Property:

• Vapor Pressure: 0.000415mmHg at 25°C
• Boiling Point: 326.2°C at 760 mmHg
• Flash Point: 151.1°C
• PSA: 13.59000
• Density: 1.40 g/mL at 25 °C
• LogP: 3.42920

Purity/Quality:

98%,99%, ^*data from raw suppliers

Bromodiphenylphosphine 96% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: F,C
• Statements: 14-34
• Safety Statements: 26-36/37/39-43-45

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Bromodiphenylphosphine 96%

There total 9 articles about Bromodiphenylphosphine 96% which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

tetraphenyldiphosphine oxide (2096-83-5) → complex of tetraphenyldiphosphine with tin tetrabromide + complex of bis(diphenyldiphosphinic) anhydride with tin tetrabromide + Bromodiphenylphosphin (1079-65-8)

Guidance literature:

With stannic bromide; In dichloromethane; at 30 - 35 ℃; for 72h; Product distribution; Mechanism; var. rati of reagents;

Reference yield: 72.0%

chloro-diphenylphosphine (1079-66-9,74391-44-9) → Bromodiphenylphosphin (1079-65-8)

Guidance literature:

With phosphorus tribromide;

DOI:10.1021/jo00372a016

Reference yield:

Tetraphenyldiphosphin (1101-41-3) → Bromodiphenylphosphin (1079-65-8)

Guidance literature:

With bromine;

upstream raw materials:

chloro-diphenylphosphine

Tetraphenyldiphosphin

bromobenzene

tetraphenyldiphosphine oxide

Downstream raw materials:

<(diphenylphosphinothioyl)tosylmethylene>triphenylphosphorane

benzyldiphenylphosphine oxide

di-tert-butylphosphine

Tetraphenyldiphosphin

Refernces

• 1、 Vincent, E.,Verdonck, L.,Kelen, G. P. van der. "NMR STUDY OF (C6H5)3-nPXn (X = Cl, Br, I; n = 0-3) AND (C6H5)3-nPXnCr(CO)5 COMPOUNDS". . p. 239 - 248. Retrieved 1980.
• 2、 Verdonck, L.,Ryck, P. H. de,Roelandt, F. F.,Kelen, G. P. van der. "Vibrational study of diphenylphosphorus halides Ph2PX (X = Cl, Br, I)". . p. 299 - 302. Retrieved 1984.
• 3、 Dabkowski, Wojciech,Ozarek, Alfred,Olejniczak, Sebastian,Cypryk, Marek,Chojnowski, Julian,Michalski, Jan. "Studies on the efficient generation of phosphorus-carbon bonds via a rearrangement of PIII esters catalysed by trimethylhalosilanes". body text. p. 1747 - 1756. Retrieved 2009/09/25.