Nitroxide, diphenyl

Base Information

• Chemical Name: Nitroxide, diphenyl
• CAS No.: 712-51-6
• Molecular Formula: C12H10 N O
• Molecular Weight: 184.218
• Mol file: 712-51-6.mol

Synonyms:Diphenylnitroxide

Chemical Property of Nitroxide, diphenyl

Chemical Property:

• PSA: 3.24000
• LogP: 3.17020

Purity/Quality:

99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Diphenyl Nitroxide is a metabolite of Nitrosodiphenylamine. Studies suggest that Diphenyl Nitroxide is mediated by autoxidn. rather than by enzymic catalysis.

Technology Process of Nitroxide, diphenyl

There total 17 articles about Nitroxide, diphenyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

N-Phenylhydroxylamine (100-65-2) → Diphenylaminoxid-Radikal (712-51-6) + Nitrosobenzene (586-96-9)

Guidance literature:

With triphenylbismuth carbonate;

DOI:10.1039/c39800000246

Reference yield: 22.0%

N-Phenylhydroxylamine (100-65-2) + triphenylbismuth carbonate (47252-14-2) → Diphenylaminoxid-Radikal (712-51-6) + Nitrosobenzene (586-96-9)

Guidance literature:

DOI:10.1039/c39800000246

Reference yield: 22.0%

N-Phenylhydroxylamine (100-65-2) + triphenylbismuth carbonate (47252-14-2) → ((C6H5)2Bi)2OOCO + Diphenylaminoxid-Radikal (712-51-6) + Nitrosobenzene (586-96-9)

Guidance literature:

DOI:10.1039/c39800000246

upstream raw materials:

Nitrosobenzene

bromobenzene

t-butylnitrite

benzenediazonium tetrafluoroborate

Downstream raw materials:

diphenylamine

N-phenyl-p-benzoquinone imine N-oxide

p-nitrodiphenylnitrosamine

N-nitrosodiphenylamine

Refernces

• 1、 Astolfi, Paola,Carloni, Patricia,Damiani, Elisabetta,Greci, Lucedio,Marini, Milvia,Rizzoli, Corrado,Stipa, Pierluigi. "Reactions of nitrosoarenes with nitrogen monoxide (nitric oxide) and nitrogen dioxide: Formation of diarylnitroxides". experimental part. p. 3279 - 3285. Retrieved 2009/04/06.
• 2、 Nozaki, Koichi,Naito, Akira,Hatano, Hiroyuki,Okazaki, Satoshi. "Secondary Spin Adducts Derived from Aryl Radicals and 2-Methyl-2-nitrosopropane. Radical Chromato-ESR Spectroscopy and Numerical Decoupling Analysis Studies". . p. 113 - 119. Retrieved 2007/10/02.