n-butyl mercaptide

Base Information

• Chemical Name: n-butyl mercaptide
• CAS No.: 20733-16-8
• Molecular Formula: C4H9 S
• Molecular Weight: 89.1815
• Mol file: 20733-16-8.mol

Synonyms:1-Butanethiolate;Butanethiolate; Butyl mercaptide; Butyl mercaptyl anion

Chemical Property of n-butyl mercaptide

Chemical Property:

• Vapor Pressure: 46.3mmHg at 25°C
• Boiling Point: 98.2°Cat760mmHg
• Flash Point: 12.8°C
• PSA: 0.00000
• Density: g/cm³
• LogP: 1.33340

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of n-butyl mercaptide

There total 6 articles about n-butyl mercaptide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

n-butanethiol (109-79-5) + C6H6P(1-) → n-butyl mercaptyl anion (20733-16-8) + phenylphosphane (638-21-1)

Guidance literature:

at 57.84 ℃; Equilibrium constant; Gas phase;

DOI:10.1002/chem.200802307

Reference yield:

C12H16NO2S(1-) → n-butyl mercaptyl anion (20733-16-8) + (2-nitroethenyl)benzene (102-96-5) + butyl(2-nitro-1-phenylethyl)sulfane (110130-38-6)

Guidance literature:

With acetic acid; In water; acetonitrile; Rate constant; Equilibrium constant; acetate buffer; pH-jump experiments;

DOI:10.1021/jo00034a032

Reference yield:

C15H17N2OS(1-) → n-butyl mercaptyl anion (20733-16-8) + 2-(methoxyphenylmethylene)malononitrile (42754-56-3)

Guidance literature:

With potassium chloride; In dimethyl sulfoxide; at 20 ℃; pH=11.76 - 12.31; Equilibrium constant;

DOI:10.1021/ja003536t

upstream raw materials:

n-butanethiol

Downstream raw materials:

n-butanethiol

dibutyl disulfide

3-carboxy-4-nitrobenzenethiolate

Refernces

• 1、 Bernasconi,Ketner,Ragains,Chen,Rappoport. "Unraveling structure-reactivity relationships in SNV reactions: Kinetics of the reactions of methoxybenzylidenemalononitrile, 2-(methylthiobenzylidene)- 1,3-indandione, 2-(benzylthiobenzylidene)-1,3-indandione, and methyl β-methylthio-α-nitroci". . p. 2155 - 2164. Retrieved 2007/10/03.
• 2、 Bernasconi, Claude F.,Schuck, David F.. "Kinetics of Reversible Thiolate Ion Addition to Substituted β-Nitrostyrenes in Water. Radicaloid Transition State or Principle of Nonperfect Synchronization?". . p. 2365 - 2373. Retrieved 2007/10/02.