dimethyl (2E,4Z)-2,5-dimethylhexa-2,4-dienedioate

Base Information

Chemical Name:dimethyl (2E,4Z)-2,5-dimethylhexa-2,4-dienedioate
CAS No.:23119-30-4
Molecular Formula:C10H14 O4
Molecular Weight:198.219
Hs Code.:
NSC Number:141077
Mol file:23119-30-4.mol

Synonyms:23119-30-4;NSC141077;NSC-141077

Suppliers and Price of dimethyl (2E,4Z)-2,5-dimethylhexa-2,4-dienedioate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 4 raw suppliers

Chemical Property of dimethyl (2E,4Z)-2,5-dimethylhexa-2,4-dienedioate

Chemical Property:

Vapor Pressure:0.00331mmHg at 25°C
Boiling Point:282.7°C at 760 mmHg
Flash Point:135.6°C
Density:1.057g/cm³
XLogP3:1.6
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:5
Exact Mass:198.08920892
Heavy Atom Count:14
Complexity:257

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(=CC=C(C)C(=O)OC)C(=O)OC
Isomeric SMILES:C/C(=C\C=C(\C)/C(=O)OC)/C(=O)OC

Technology Process of dimethyl (2E,4Z)-2,5-dimethylhexa-2,4-dienedioate

There total 16 articles about dimethyl (2E,4Z)-2,5-dimethylhexa-2,4-dienedioate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 52.0%

: 2605-68-7
methyl 2-(triphenylphosphoranylidene)propionate

: 54354-54-0
(E),(Z)-2,5-Di(metoxycarbonyl)-hexa-2,4-dien

: 23119-30-4
(E),(E)-2,5-Di(methoxycarbonyl)-hexa-2,4-dien

Guidance literature:: In toluene; at 110 ℃; for 4h;

Reference yield:

: 80-62-6,114512-63-9,143476-91-9,25188-98-1,9011-14-7
methacrylic acid methyl ester

: 23119-30-4
(E),(E)-2,5-Di(methoxycarbonyl)-hexa-2,4-dien

: 4513-62-6
dimethyl 2-methyl-5-methylenehexanodioate

: 22946-43-6
(E)-methyl-2-methyl-3-phenylacrylate

: (E)-2,5-Di (methoxycarbonyl)-pent-2-en

: 88598-80-5
(E)-2,5-Di(methoxycarbonyl)-hexa-3-en

Guidance literature:: bis(benzonitrile)palladium(II) dichloride; silver tetrafluoroborate; In acetonitrile; Mechanism; Product distribution; various catalysts, catalytic dimerizatio and codimerization by Pd-complexes, various temperature, competition reaction with methylacrylate;

Reference yield:

: 80-62-6,114512-63-9,143476-91-9,25188-98-1,9011-14-7
methacrylic acid methyl ester

: 24407-02-1
(Z,Z)-2,5-Dimethylmuconsaeuredimethylester

: 54354-54-0
(E),(Z)-2,5-Di(metoxycarbonyl)-hexa-2,4-dien

: 23119-30-4
(E),(E)-2,5-Di(methoxycarbonyl)-hexa-2,4-dien

Guidance literature:: With silver hexafluoroantimonate; [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂; copper(II) acetate monohydrate; In 1,2-dichloro-ethane; at 140 ℃; for 24h; Overall yield = 21 percent; Inert atmosphere;
DOI:10.1039/d1cy01282g