2-Iodonaphthalene

Base Information

• Chemical Name: 2-Iodonaphthalene
• CAS No.: 612-55-5
• Molecular Formula: C10H7I
• Molecular Weight: 254.07
• Hs Code.: 2903999090
• European Community (EC) Number: 627-170-4
• NSC Number: 3786
• DSSTox Substance ID: DTXSID00210107
• Nikkaji Number: J43.525B
• Wikidata: Q83084670
• Mol file: 612-55-5.mol

Synonyms:2-Iodonaphthalene;612-55-5;Naphthalene, 2-iodo-;beta-Iodonaphthalene;2-iodo-naphthalene;.beta.-Iodonaphthalene;MFCD00021590;2-iodonapthalene;NSC3786;2-iodo-naphtalene;2-Naphthyl iodide;YSWG296;SCHEMBL150366;AMY849;DTXSID00210107;BCP13447;NSC 3786;NSC-3786;AKOS009319650;CS-W005581;DS-4990;s11969;2-Iodonaphthalene, >=99.0% (HPLC);SY103936;BB 0220370;FT-0632554;I1151;A833125;AC-907/25004996

Chemical Property of 2-Iodonaphthalene

Chemical Property:

• Vapor Pressure: 0.001mmHg at 25°C
• Melting Point: 52-56 °C
• Refractive Index: 1.712
• Boiling Point: 307.5 °C at 760 mmHg
• Flash Point: 138.4 °C
• PSA: 0.00000
• Density: 1.744 g/cm³
• LogP: 3.44440
• Storage Temp.: Keep in dark place,Sealed in dry,Room Temperature
• XLogP3: 4.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 253.95925
• Heavy Atom Count: 11
• Complexity: 133

Purity/Quality:

97% ^*data from raw suppliers

2-Iodonaphthalene ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi,N
• Statements: 36/37/38-51/53
• Safety Statements: 26-61

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C2C=C(C=CC2=C1)I

Technology Process of 2-Iodonaphthalene

There total 8 articles about 2-Iodonaphthalene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

pentanonitrile (110-59-8) + naphthalene-2-boronic acid (32316-92-0) → 2-naphthalenecarbonitrile (613-46-7) + 2-iodonaphthalene (612-55-5)

Guidance literature:

With N-iodo-succinimide; 1,10-Phenanthroline; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; 1,1,1,2,2,2-hexamethyldisilane; oxygen; copper diacetate; diisopropylamine; at 20 - 150 ℃; Schlenk technique;

DOI:10.1002/chem.201501823

Reference yield: 50.0%

naphthalene (91-20-3,71998-51-1,72931-45-4) → 2-iodonaphthalene (612-55-5) + 1-Iodonaphthalene (90-14-2)

Guidance literature:

With N-iodo-succinimide; toluene-4-sulfonic acid; at 20 ℃; for 2.16667h;

DOI:10.1007/s11178-005-0256-1

Reference yield: 27.0%

Isobutyronitrile (78-82-0) + naphthalene-2-boronic acid (32316-92-0) → 2-naphthalenecarbonitrile (613-46-7) + 2-iodonaphthalene (612-55-5)

Guidance literature:

With N-iodo-succinimide; 1,10-Phenanthroline; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; 1,1,1,2,2,2-hexamethyldisilane; oxygen; copper diacetate; diisopropylamine; at 20 - 150 ℃; for 75h; Schlenk technique;

DOI:10.1002/chem.201501823

upstream raw materials:

naphthalene

2-iodonaphthalene - picric acid complex

2-dichloroiodanyl-naphthalene

acetic acid

Downstream raw materials:

1-naphthalen-1-yl-piperidine

N-(2-naphthyl)piperidine

2,2'-binaphthalene

2-(naphthalen-2-yl)benzoic acid