(E)-1-((Ethoxycarbonyl)oxy)-1,2,5,6-tetrahydro-3-pyridinecarboxaldehyde 3-(O-methyloxime)

Base Information

Chemical Name:(E)-1-((Ethoxycarbonyl)oxy)-1,2,5,6-tetrahydro-3-pyridinecarboxaldehyde 3-(O-methyloxime)
CAS No.:145071-55-2
Molecular Formula:C₁₀H₁₆N₂O₄
Molecular Weight:228.248
Hs Code.:
Mol file:145071-55-2.mol

Synonyms:BRN 5814772;(E)-1-((Ethoxycarbonyl)oxy)-1,2,5,6-tetrahydro-3-pyridinecarboxaldehyde 3-(O-methyloxime);3-Pyridinecarboxaldehyde, 1,2,5,6-tetrahydro-1-((ethoxycarbonyl)oxy)-, 3-(O-methyloxime), (E)-;145071-55-2;LS-130492

Suppliers and Price of (E)-1-((Ethoxycarbonyl)oxy)-1,2,5,6-tetrahydro-3-pyridinecarboxaldehyde 3-(O-methyloxime)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (E)-1-((Ethoxycarbonyl)oxy)-1,2,5,6-tetrahydro-3-pyridinecarboxaldehyde 3-(O-methyloxime)

Chemical Property:

Vapor Pressure:0.001mmHg at 25°C
Boiling Point:300.813°C at 760 mmHg
Flash Point:135.727°C
Density:1.167g/cm³
XLogP3:1.6
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:6
Rotatable Bond Count:6
Exact Mass:228.11100700
Heavy Atom Count:16
Complexity:289

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCOC(=O)ON1CCC=C(C1)C=NOC
Isomeric SMILES:CCOC(=O)ON1CCC=C(C1)/C=N/OC

Technology Process of (E)-1-((Ethoxycarbonyl)oxy)-1,2,5,6-tetrahydro-3-pyridinecarboxaldehyde 3-(O-methyloxime)

There total 3 articles about (E)-1-((Ethoxycarbonyl)oxy)-1,2,5,6-tetrahydro-3-pyridinecarboxaldehyde 3-(O-methyloxime) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

: 541-41-3
chloroformic acid ethyl ester

: 121750-98-9
1-hydroxy-1,2,5,6-tetrahydropyridine-3-carboxaldehyde-O-methyloxime

: 121750-84-3,145071-55-2
1-ethoxycarbonyloxy-1,2,5,6-tetrahydropyridine-3-carboxaldehyde-O-methyloxime

Guidance literature:: With triethylamine; In tetrahydrofuran; for 0.166667h; Ambient temperature;
DOI:10.1016/0223-5234(92)90186-5

Reference yield:

: 72989-57-2
pyridine-3-carboxaldehyde-O-methyloxime-N-oxide

: 121750-84-3,145071-55-2
1-ethoxycarbonyloxy-1,2,5,6-tetrahydropyridine-3-carboxaldehyde-O-methyloxime

Guidance literature:: Multi-step reaction with 2 steps

1: NaBH₄ / methanol / 1 h / Ambient temperature

2: 73 percent / triethylamine / tetrahydrofuran / 0.17 h / Ambient temperature

With sodium tetrahydroborate; triethylamine; In tetrahydrofuran; methanol;
DOI:10.1016/0223-5234(92)90186-5