2,3,4,6-Tetra-o-acetyl-1-s-benzoyl-1-thiohexopyranose

Base Information

Chemical Name:2,3,4,6-Tetra-o-acetyl-1-s-benzoyl-1-thiohexopyranose
CAS No.:6767-60-8
Molecular Formula:C21H24O10S
Molecular Weight:468.4743
Hs Code.:
NSC Number:89879
DSSTox Substance ID:DTXSID40293494

Synonyms:6767-60-8;NSC89879;2,3,4,6-tetra-o-acetyl-1-s-benzoyl-1-thiohexopyranose;DTXSID40293494;NSC-89879

Suppliers and Price of 2,3,4,6-Tetra-o-acetyl-1-s-benzoyl-1-thiohexopyranose

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 5 raw suppliers

Chemical Property of 2,3,4,6-Tetra-o-acetyl-1-s-benzoyl-1-thiohexopyranose

Chemical Property:

Vapor Pressure:1.75E-11mmHg at 25°C
Boiling Point:534.1°C at 760 mmHg
Flash Point:257.8°C
Density:1.34g/cm³
XLogP3:2.8
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:11
Rotatable Bond Count:12
Exact Mass:468.10901813
Heavy Atom Count:32
Complexity:717

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(=O)OCC1C(C(C(C(O1)SC(=O)C2=CC=CC=C2)OC(=O)C)OC(=O)C)OC(=O)C

Technology Process of 2,3,4,6-Tetra-o-acetyl-1-s-benzoyl-1-thiohexopyranose

There total 5 articles about 2,3,4,6-Tetra-o-acetyl-1-s-benzoyl-1-thiohexopyranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 1616373-74-0
triisopropylsilyl 2,3,4,6-tetra-O-acetyl-1-thio-β-D-glucopyranoside

: 98-88-4
benzoyl chloride

: 6767-60-8
2,3,4,6-tetra-O-acetyl-1-S-benzoyl-1-thio-β-D-glucopyranose

Guidance literature:: With tetrabutyl ammonium fluoride; In tetrahydrofuran; acetonitrile; at 20 ℃; for 0.0833333h; stereoselective reaction; Inert atmosphere;
DOI:10.1039/c4ob00741g

Reference yield: 73.0%

: 65-85-0,8013-63-6
benzoic acid

: 572-09-8
2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide

: 6767-60-8
2,3,4,6-tetra-O-acetyl-1-S-benzoyl-1-thio-β-D-glucopyranose

Guidance literature:: benzoic acid; With N-Bromosuccinimide; triphenylphosphine; In chloroform; at 28 ℃;

With benzyltriethylammonium tetrathiomolybdate; In chloroform; at 28 ℃;

2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide; In chloroform; at 28 ℃;
DOI:10.1021/jo9009694

Reference yield:

: 98-91-9
thiobenzoic acid

: 572-09-8
2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide

: 6767-60-8
2,3,4,6-tetra-O-acetyl-1-S-benzoyl-1-thio-β-D-glucopyranose

Guidance literature:: thiobenzoic acid; With potassium hydroxide; In methanol; for 2h; Inert atmosphere;

2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide; In acetone; at 20 ℃; Inert atmosphere;
DOI:10.1021/acs.orglett.1c01723