phosphorus(1+), trifluorohydro-, iron salt

Base Information

• Chemical Name: phosphorus(1+), trifluorohydro-, iron salt
• CAS No.: 13815-34-4
• Molecular Formula: F₁₅FeP₅
• Molecular Weight: 495.692
• Mol file: 13815-34-4.mol

Synonyms:Iron,pentakis(phosphorus trifluoride)- (7CI,8CI); Phosphorous trifluoride, ironcomplex; Pentakis(trifluorophosphine)iron

Chemical Property of phosphorus(1+), trifluorohydro-, iron salt

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Density: g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of phosphorus(1+), trifluorohydro-, iron salt

There total 3 articles about phosphorus(1+), trifluorohydro-, iron salt which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

iron pentacarbonyl (13463-40-6,37220-42-1) + trifluorophosphane (7783-55-3) + sulfur(VI) hexafluoride (2551-62-4) → {Fe(CO)4(PF3)} (16388-47-9,35739-13-0,53368-95-9) + {Fe(CO)3(PF3)2} (17594-23-9,17594-22-8,16454-87-8,53275-22-2) + {Fe(CO)2(PF3)3} (17594-25-1,17594-26-2,16388-46-8,53275-23-3) + {Fe(CO)(PF3)4} (17594-28-4,16388-45-7,17594-29-5) + {Fe(PF3)5} (13815-34-4)

Guidance literature:

In gas; byproducts: CO; other Radiation; irradiation of mixture of SF6 (0.5 Torr), Fe(CO)5 (0.2 Torr) and PF3 (10 Torr); gas chromy.;

DOI:10.1021/ja00189a007

Reference yield:

bis(pentadienyl)iron (74910-62-6) + trifluorophosphane (7783-55-3) → Fe(PF3)5 (13815-34-4)

Guidance literature:

In hexane; soln. Fe(C5H7)2 in hexane degassed and frozen at -196°C under vac., PF3 condensed, mixt. heated to 60°C and stirred for 1 day; product identified by NMR;

Reference yield:

iron pentacarbonyl (13463-40-6,37220-42-1) + trifluorophosphane (7783-55-3) → {Fe(CO)4(PF3)} (16388-47-9,35739-13-0,53368-95-9) + {Fe(CO)3(PF3)2} (17594-23-9,17594-22-8,16454-87-8,53275-22-2) + {Fe(CO)2(PF3)3} (17594-25-1,17594-26-2,16388-46-8,53275-23-3) + {Fe(CO)(PF3)4} (17594-28-4,16388-45-7,17594-29-5) + Fe(PF3)5 (13815-34-4)

Guidance literature:

stainless steel bomb, 14-35 atm, 18h, PF3 rich products dominate at 240-300°C, CO rich ones below 200°C; pumping in vac. into a cold trop, at (-78--195°C) or distillation at room temp.;

DOI:10.1021/ic50020a011

upstream raw materials:

iron pentacarbonyl

trifluorophosphane

sulfur(VI) hexafluoride

bis(pentadienyl)iron

Refernces

• 1、 Severson, Sarah J.,Cymbaluk, Teddy H.,Ernst, Richard D.,Higashi, John M.,Parry, Robert W.. "Bis(allyl)nickel and bis(pentadienyl)iron as precursors for the synthesis of Ni(PF3)4, Ni(PF2H)4, and Fe(PF3)5 [2]". . p. 3833 - 3834. Retrieved 2008/10/08.