trithiomolybdic acid

Base Information

• Chemical Name: trithiomolybdic acid
• CAS No.: 19452-56-3
• Molecular Formula: MoOS₃
• Molecular Weight: 208.137
• Mol file: 19452-56-3.mol

Synonyms:Thiomolybdate(MoOS32-) (8CI); Oxotrithioxomolybdate(2-)

Chemical Property of trithiomolybdic acid

Chemical Property:

• PSA: 49.16000
• LogP: 0.52460

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of trithiomolybdic acid

There total 3 articles about trithiomolybdic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

sodium molybdate + sodiumsulfide nonahydrate → trithiomolybdate(2-) (19452-56-3) + tetrathiomolybdate(VI) (16330-92-0)

Guidance literature:

With catalyst: 2-mercaptoethanol; In water; under Ar; pH=9; room temperature; excess of 2-mercaptoethanol and S(2-); monitoring by UV; not isolated;

DOI:10.1016/S0020-1693(00)93461-3

Reference yield:

sodium sulfide (1313-82-2) + molybdenum(VI) ion → monothiomolybdate(2-) (25326-93-6) + dithiomolybdate(2-) (16608-22-3) + trithiomolybdate(2-) (19452-56-3) + tetrathiomolybdate(VI) (16330-92-0)

Guidance literature:

With sodium hydrogencarbonate; In water; determination of stability constants of the thiomolydates at 298.-+.1K and pH 8.5-10.5;; not isolated, detected by UV-spectroscopy;;

Reference yield:

ammonium molybdate + thiourea (17356-08-0) → trithiomolybdate(2-) (19452-56-3)

Guidance literature:

In water; at 400 ℃; Temperature; Flow reactor;

DOI:10.1039/c4cc10158h

upstream raw materials:

sodium sulfide

thiourea

Refernces