(Dioxygen)bis(triphenylphosphine)platinum

Base Information

Chemical Name:(Dioxygen)bis(triphenylphosphine)platinum
CAS No.:15614-67-2
Molecular Formula:C36H30 O2 P2 Pt
Molecular Weight:751.661
Hs Code.:
European Community (EC) Number:239-692-6

Synonyms:(Dioxygen)bis(triphenylphosphine)platinum

Suppliers and Price of (Dioxygen)bis(triphenylphosphine)platinum

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 7 raw suppliers

Chemical Property of (Dioxygen)bis(triphenylphosphine)platinum

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:6
Exact Mass:751.136899
Heavy Atom Count:41
Complexity:202

Purity/Quality:: 98%Min ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.[O-2].[O-2].[Pt+4]

Technology Process of (Dioxygen)bis(triphenylphosphine)platinum

There total 3 articles about (Dioxygen)bis(triphenylphosphine)platinum which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 10199-34-5,14056-88-3,15604-36-1
cis-dichlorobis(triphenylphosphine)platinum(II)

: 15614-67-2
(η2-peroxo)bis(triphenylphosphine)platinum

: 791-28-6
Triphenylphosphine oxide

Guidance literature:: With oxygen; In acetonitrile; benzene; Electrolysis; dissolving cis-(PtCl2(PPh3)2) in preelectrolyzed acetonitrile/benzene (5/2 v/v, containing 0.1 M TBAP, under N2), electrolysis to zero current at -1.60 V (2 - 3 h, Ar-atmosphere, room temp.), bubbling O2 through soln. (30 min, room temp.); evapg. (in vacuo), extg. (benzene), filtering, concg.;
DOI:10.1021/om00106a032

Reference yield:

: 14221-02-4
tetrakis(triphenylphosphine)platinum

: 80937-33-3
oxygen

: 15614-67-2
(η2-peroxo)bis(triphenylphosphine)platinum

Guidance literature:: In N,N-dimethyl-formamide; oxygenation of solution at 25.+-.2 °C; detd. by (1)H and (31)P NMR, UV/Vis spectroscopy; Kinetics;
DOI:10.1002/anie.200502096

Reference yield:

: 133774-07-9,14781-83-0,27285-43-4
cis-[bis(triphenylphosphane)diazidoplatinum(II)]

: 15614-67-2
(η2-peroxo)bis(triphenylphosphine)platinum

Guidance literature:: With oxygen; In not given; byproducts: N2; Irradiation (UV/VIS); O2 atmosphere; flash photolysis; not isolated; UV/VIS monitoring;