P(c1ccccc1)(c2ccccc2)(c3ccccc3)[Pt](Cl)(Cl)P(c4ccccc4)(c5ccccc5)c6ccccc6

Base Information

• Chemical Name: P(c1ccccc1)(c2ccccc2)(c3ccccc3)[Pt](Cl)(Cl)P(c4ccccc4)(c5ccccc5)c6ccccc6
• CAS No.: 10199-34-5
• Molecular Formula: C₃₆H₃₀Cl₂P₂Pt
• Molecular Weight: 790.568
• NSC Number: 168797,162923
• Mol file: 10199-34-5.mol

Synonyms:NSC168797;P(c1ccccc1)(c2ccccc2)(c3ccccc3)[Pt](Cl)(Cl)P(c4ccccc4)(c5ccccc5)c6ccccc6;SCHEMBL691328;NSC162923;NSC-162923;NSC-168797;CS-0085661

Chemical Property of P(c1ccccc1)(c2ccccc2)(c3ccccc3)[Pt](Cl)(Cl)P(c4ccccc4)(c5ccccc5)c6ccccc6

Chemical Property:

• Melting Point: 308 °C (decomp)
• Boiling Point: 360 °C at 760 mmHg
• Flash Point: 181.7 °C
• PSA: 27.18000
• LogP: -5.09690
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 6
• Exact Mass: 791.100425
• Heavy Atom Count: 41
• Complexity: 490

Purity/Quality:

98%,99%, ^*data from raw suppliers

cis-Bis(triphenylphosphine)platinum (II) chloride B7853H ? cis-Bis(triphenylphosphine)platinum (II) chloride ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)[PH+](C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)[PH+](C2=CC=CC=C2)C3=CC=CC=C3.Cl[Pt]Cl

Technology Process of P(c1ccccc1)(c2ccccc2)(c3ccccc3)[Pt](Cl)(Cl)P(c4ccccc4)(c5ccccc5)c6ccccc6

There total 193 articles about P(c1ccccc1)(c2ccccc2)(c3ccccc3)[Pt](Cl)(Cl)P(c4ccccc4)(c5ccccc5)c6ccccc6 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

potassium tetrachloroplatinate(II) (10025-99-7) + triphenylphosphine (603-35-0) → cis-dichlorobis(triphenylphosphine)platinum(II) (10199-34-5,14056-88-3,15604-36-1)

Guidance literature:

Ar atmosphere; procedure described by Brune et al., Chem. Ber. 117 (1984) 2791-2802;

Reference yield: 98.0%

dihydrogen hexachloroplatinate(IV) hexahydrate → cis-dichlorobis(triphenylphosphine)platinum(II) (10199-34-5,14056-88-3,15604-36-1)

Guidance literature:

With triphenylphosphine; In ethanol; molar ratio Pt:P=1:4.5; stirring (room temp., few min), refluxing (1 h); pptn. on cooling, filtration, washing (EtOH, ether), drying (vac.);

DOI:10.1016/S0020-1693(00)88569-2

Reference yield: 98.0%

triphenylphosphine (603-35-0) + platinum(II) chloride (10025-65-7) → cis-dichlorobis(triphenylphosphine)platinum(II) (10199-34-5,14056-88-3,15604-36-1)

Guidance literature:

In neat (no solvent); ball-milling of crystalline PtCl2 with PPh3 (2 molar equiv.) at room temp. for 1 or 2 h; powder dissolved in CH2Cl2, soln. filtered, solvent evapd.;

DOI:10.1039/b203694k

upstream raw materials:

triphenylphosphine

ethylenebis(triphenylphosphine)platinum⁽⁰⁾

potassium trichloro(ethene)platinate(II)

tetrachloromethane

Downstream raw materials:

dichloro bis(acetonitrile) palladium(II)

Pt(P(C₆H₅)3)2(NO₂)Cl

tetrakis(triphenylphosphine)platinum

((C₆H₅)3P)2PtClF

Refernces

• 1、 Dol, Georg C.,Gaemers, Sander,Hietikko, Marko,Kamer, Paul C. J.,Van Leeuwen, Piet W. N. M.,Nolte, Roeland J. M.. "Binding Properties of Two Novel Phosphane-Modified Tetrapodants and Their Bimetallic Transition Metal Complexes". . p. 1975 - 1985. Retrieved 1998.
• 2、 Busetto, Luigi. "PLATINUM(II) AND PALLADIUM(II) COMPLEXES OF THIACYCLOOCT-4-ENES; AN UNUSUAL METAL-CATALYZED OLEFIN ISOMERIZATION". . p. 411 - 418. Retrieved 1980.
• 3、 Monica, G. La,Cenini, S.. "". . p. L17 - L18. Retrieved 1977.
• 4、 Leigh, G. Jeffery,McKenna, Charles E.,Mc Mahon, C. Niamh. "Protonation of cyclopropene complexes of platinum(0) and the reduction of cyclopropene by nitrogenases". . p. 193 - 201. Retrieved 1998.
• 5、 Suenkel, Karlheinz. "Komplexchemie perhalogenierter Cyclopentadiene und Alkine. IX. Darstellung einiger Phosphoniumacetylid-Komplexe und Struktur von (Ph3P)Cl2Pd(CCPPh3)". . p. 101 - 108. Retrieved 1992.
• 6、 Cavinato, G.,Toniolo, L.. "". . p. 39 - 42. Retrieved 1981.
• 7、 Crociani, Bruno,Bianca, Francesca Di,Giovenco, Amalia,Berton, Adriano,Bertani, Roberta. "Preparation and reactions of 2-pyridylplatinum(II) complexes 2)(L)2> (L = tertiary phosphine). Compounds with a markedly nucleophilic pyridine nitrogen atom.". . p. 255 - 268. Retrieved 1989.
• 8、 Stang, Peter J.,Song, Linsheng,Halton, Brian. "Metallacyclobutarenes from cyclopropanaphthalene: reactions with rhodium(I), platinum(0) and palladium(0)". . p. 215 - 220. Retrieved 1990.
• 9、 Eremenko,Kurasov,Virovets,Struchkov,Bashilov,Sokolov. "Synthesis of platinum-mercury clusters and the molecular structure of Pt4(HgBr)2(μ-CO)4(PPh3) 4". . p. 164 - 167. Retrieved 1997.
• 10、 Bashilov, V. V.,Mednikov, E. G.,Kurasov, S. S.,Petrovskii, P. V.,Eremenko, N. K.,Sokolov, V. I.. "". . . Retrieved 1987.