7-Bromo-1-nitronaphthalene

Base Information

• Chemical Name: 7-Bromo-1-nitronaphthalene
• CAS No.: 102153-49-1
• Molecular Formula: C10H6BrNO2
• Molecular Weight: 252.06400
• DSSTox Substance ID: DTXSID30356542
• Wikidata: Q82135936
• Mol file: 102153-49-1.mol

Synonyms:7-bromo-1-nitronaphthalene;102153-49-1;Naphthalene, 7-bromo-1-nitro-;2-bromo-8-nitro-naphthalene;SCHEMBL5781732;DTXSID30356542;FT-0710158

Chemical Property of 7-Bromo-1-nitronaphthalene

Chemical Property:

• Boiling Point: 363.8±17.0 °C(Predicted)
• PSA: 45.82000
• Density: 1.662±0.06 g/cm3(Predicted)
• LogP: 4.03370
• XLogP3: 3.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 250.95819
• Heavy Atom Count: 14
• Complexity: 229

Purity/Quality:

97% ^*data from raw suppliers

7-BROMO-1-NITRONAPHTHALENE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C1=CC2=C(C=C(C=C2)Br)C(=C1)[N+](=O)[O-]

Technology Process of 7-Bromo-1-nitronaphthalene

There total 5 articles about 7-Bromo-1-nitronaphthalene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 29.0%

2-bromonaphthalene (580-13-2) → 2-bromo-1-nitronaphthalene (4185-62-0) + 2-bromo-8-nitronaphthalene (102153-49-1)

Guidance literature:

With nitric acid; acetic acid; at 60 ℃; for 2h;

DOI:10.1016/S0040-4020(01)89289-9

Reference yield: 15.0%

2-bromonaphthalene (580-13-2) → 2-bromo-8-nitronaphthalene (102153-49-1)

Guidance literature:

With nitric acid; acetic acid; at 60 ℃; for 2h;

Reference yield:

8-nitro-2-naphthylamine (607-38-5) → 2-bromo-8-nitronaphthalene (102153-49-1)

Guidance literature:

With sulfuric acid; acetic acid; Diazotization_.Behandlung der Diazoniumsalz-Loesung mit CuBr in konz. wss. HBr;

DOI:10.1021/ja01172a071

upstream raw materials:

2-bromonaphthalene

8-nitro-2-naphthylamine

nitric acid

Downstream raw materials:

1,7‐dibromonaphthalene

Refernces

• 1、 -. "Substituted imidazol-pyridazine derivatives". Page 22. . Retrieved 2010/02/05.