Stannane, (2-phenyl-1-propenylidene)bis[trimethyl-

Base Information

Chemical Name:Stannane, (2-phenyl-1-propenylidene)bis[trimethyl-
CAS No.:103670-46-8
Molecular Formula:C₁₅H₂₆Sn₂
Molecular Weight:443.791
Hs Code.:

Synonyms:

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Chemical Property of Stannane, (2-phenyl-1-propenylidene)bis[trimethyl-

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Technology Process of Stannane, (2-phenyl-1-propenylidene)bis[trimethyl-

There total 1 articles about Stannane, (2-phenyl-1-propenylidene)bis[trimethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

: 17946-71-3
(trimethylstannyl)lithium

: 60014-86-0
(2,2-dibromo 1-methylethenyl)benzene

: 103670-46-8
(CH₃)(C₆H₅)CC(Sn(CH₃)3)2

Guidance literature:: In tetrahydrofuran; byproducts: LiBr; Ar atmosphere, addn. Sn-compd. to soln. of dibromoalkane (temp. < -70°C); addn. water (room temp.), extn. (ether), drying (MgSO4), removal THF (vac.), distn.; elem. anal.;

Reference yield: 43.0%

: 103670-46-8
(CH₃)(C₆H₅)CC(Sn(CH₃)3)2

: 1631-73-8
trimethylstannane

: 103670-67-3
(CH₃)(C₆H₅)HCC(Sn(CH₃)3)3

Guidance literature:: In neat (no solvent); Irradiation (UV/VIS); Ar atmosphere, irradiation (Hg lamp, room temp., quartz tube); extn. (CH2Cl2), filtration, solvent removal, sublimation; elem. anal.;

Reference yield: 40.0%

: 103670-46-8
(CH₃)(C₆H₅)CC(Sn(CH₃)3)2

: 1520-78-1
trimethyllead chloride

: 112166-96-8
C₆H₅(CH₃)CC(Pb(CH₃)3)2

Guidance literature:: With methyllithium; In tetrahydrofuran; alkene and MeLi (1 equiv) stirred for 1 h at -78°C under Ar, Me3PbCl (1 equiv) added, after 30 min warmed to room temp., cooled to -78°C, treated with 1 equiv each of MeLi and Me3PbCl, after 30 min thesame with 0.3 equiv MeLi and Me3PbCl; water was added, org. phase sepd., dried, solvent removed, residue was distilled in vacuo;
DOI:10.1016/0022-328X(87)85003-9