Lithium, (trimethylstannyl)-

Base Information

Chemical Name:Lithium, (trimethylstannyl)-
CAS No.:17946-71-3
Molecular Formula:C3H9LiSn
Molecular Weight:170.755
Hs Code.:

Synonyms:Lithium,(trimethylstannyl);

Suppliers and Price of Lithium, (trimethylstannyl)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of Lithium, (trimethylstannyl)-

Chemical Property:

Melting Point:238-240 °C(Solv: hexane (110-54-3))
PSA：0.00000
LogP:1.10460

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Lithium, (trimethylstannyl)-

There total 6 articles about Lithium, (trimethylstannyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 10.0%

: 113688-90-7
(C₆H₅)2CC(Li)Sn(CH₃)3

: 17946-71-3
(trimethylstannyl)lithium

: 501-65-5
diphenyl acetylene

Guidance literature:: In not given; decompn. of Ph2C=C(Li)SnMe3 was examined; polymeric org. products were also observed;
DOI:10.1016/0022-328X(87)85002-7

Reference yield:

: 917-54-4
methyllithium

: 661-69-8
hexamethyldistannane

: 17946-71-3
(trimethylstannyl)lithium

: 594-27-4
tetramethylstannane

Guidance literature:: In diethyl ether; Sn2Me6 (1.12 mmol) in Et2O treated with MeLi (1.12 mmol, 1 M soln. in Et2O) under Ar, stirred for 30 min at 0°C (by method of Still, W.C. J.Am.Chem.Soc. 1977, 99, 4836); not isolated;
DOI:10.1021/om00146a021

Reference yield:

: 917-54-4
methyllithium

: 1631-73-8
trimethylstannane

: 17946-71-3
(trimethylstannyl)lithium

: (CH₃)4Sn(H)^(1-)*Li⁽¹⁺⁾=(CH₃)4Sn(H)Li

: (CH₃)5Sn^(1-)*Li⁽¹⁺⁾=(CH₃)5SnLi

: 594-27-4
tetramethylstannane

Guidance literature:: In further solvent(s); byproducts: LiH; react. of TMTH with MeLi in ether/THF/pentane/HMPA (2/2/1/0.8) at -125°C under Ar for 5 min; not isolated, mixt. of Me4Sn, Me3SnLi, and Me5SnLi in ratio 1:1:0.3 detected by NMR;
DOI:10.1021/om00146a021