Technology Process of Silane, dimethylphenyl(tributylstannyl)-
There total 1 articles about Silane, dimethylphenyl(tributylstannyl)- which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
n-butyllithium; diisopropylamine;
In
tetrahydrofuran; hexane;
THF injected into flask followed by distd. (i-Pr)2NH, cooled to -10°C, hexanes soln. of BuLi injected, stirred for 10 min, Bu3SnH injected dropwise, stirred at 0°C for 45 min, ClSiMe2Ph injected dropwise, stirred for 1 h at room temp.; GC-FID anal., evapn., filtration, washing (Et2O), distn. under vac.;
DOI:10.1016/j.molcata.2003.09.032
- Guidance literature:
-
With
tetrakis(triphenylphosphine) palladium(0); diethyl ether; 3-butyl-1-methyl-1H-imidazol-3-ium hexafluorophosphate;
In
further solvent(s);
ionic liq. (1-n-butyl-3-methylimidazolium)PF6 heated at 70°C for 4 h under vac., Pd(PPh3)4 (5 mol%) added (in Ar globe box), stirred to suspend Pd, Bu3SnSiMe2Ph, PhCCH and dry Et2O injected, heated under N2 in70°C oil bath for 96 h; GC-FID anal., washing (dry Et2O under N2), evapn., flash chromy. (hexanes);
DOI:10.1016/j.molcata.2003.09.032
- Guidance literature:
-
With
tetrakis(triphenylphosphine) palladium(0); diethyl ether; 3-butyl-1-methyl-1H-imidazol-3-ium hexafluorophosphate;
In
further solvent(s);
ionic liq. (1-n-butyl-3-methylimidazolium)PF6 heated at 70°C for 4 h under vac., Pd(PPh3)4 (5 mol%) added (in Ar globe box), stirred to suspend Pd, Bu3SnSiMe2Ph, HCC(CH2)4OTHP and Et2O injected, heated under N2 in 70°C oil bath for 168 h; GC-FID anal., washing (dry Et2O under N2), evapn., flash chromy. (hexanes);
DOI:10.1016/j.molcata.2003.09.032
