(+/-)-(Z)-2-(6-(dimethylphenylsilyl)-5-(tributylstannyl)-5-hexenyloxy)tetrahydro-2H-pyran

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Chemical Name:(+/-)-(Z)-2-(6-(dimethylphenylsilyl)-5-(tributylstannyl)-5-hexenyloxy)tetrahydro-2H-pyran
CAS No.:738591-68-9
Molecular Formula:C₃₁H₅₆O₂SiSn
Molecular Weight:607.58
Hs Code.:

Synonyms:(+/-)-(Z)-2-(6-(dimethylphenylsilyl)-5-(tributylstannyl)-5-hexenyloxy)tetrahydro-2H-pyran

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (+/-)-(Z)-2-(6-(dimethylphenylsilyl)-5-(tributylstannyl)-5-hexenyloxy)tetrahydro-2H-pyran

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Technology Process of (+/-)-(Z)-2-(6-(dimethylphenylsilyl)-5-(tributylstannyl)-5-hexenyloxy)tetrahydro-2H-pyran

There total 1 articles about (+/-)-(Z)-2-(6-(dimethylphenylsilyl)-5-(tributylstannyl)-5-hexenyloxy)tetrahydro-2H-pyran which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 1720-37-2
2-(hex-5-yn-1-yloxy)tetrahydro-2H-pyran

: 103731-36-8
dimethylphenyl(tributylstannyl)silane

: 738591-68-9
(+/-)-(Z)-2-(6-(dimethylphenylsilyl)-5-(tributylstannyl)-5-hexenyloxy)tetrahydro-2H-pyran

Guidance literature:: With tetrakis(triphenylphosphine) palladium⁽⁰⁾; diethyl ether; 3-butyl-1-methyl-1H-imidazol-3-ium hexafluorophosphate; In further solvent(s); ionic liq. (1-n-butyl-3-methylimidazolium)PF6 heated at 70°C for 4 h under vac., Pd(PPh3)4 (5 mol%) added (in Ar globe box), stirred to suspend Pd, Bu3SnSiMe2Ph, HCC(CH2)4OTHP and Et2O injected, heated under N2 in 70°C oil bath for 168 h; GC-FID anal., washing (dry Et2O under N2), evapn., flash chromy. (hexanes);
DOI:10.1016/j.molcata.2003.09.032