Technology Process of (+/-)-(Z)-2-(6-(dimethylphenylsilyl)-5-(tributylstannyl)-5-hexenyloxy)tetrahydro-2H-pyran
There total 1 articles about (+/-)-(Z)-2-(6-(dimethylphenylsilyl)-5-(tributylstannyl)-5-hexenyloxy)tetrahydro-2H-pyran which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
tetrakis(triphenylphosphine) palladium(0); diethyl ether; 3-butyl-1-methyl-1H-imidazol-3-ium hexafluorophosphate;
In
further solvent(s);
ionic liq. (1-n-butyl-3-methylimidazolium)PF6 heated at 70°C for 4 h under vac., Pd(PPh3)4 (5 mol%) added (in Ar globe box), stirred to suspend Pd, Bu3SnSiMe2Ph, HCC(CH2)4OTHP and Et2O injected, heated under N2 in 70°C oil bath for 168 h; GC-FID anal., washing (dry Et2O under N2), evapn., flash chromy. (hexanes);
DOI:10.1016/j.molcata.2003.09.032
