Thiocyanic acid, 1-methylheptyl ester, (R)-

Base Information

• Chemical Name: Thiocyanic acid, 1-methylheptyl ester, (R)-
• CAS No.: 10435-91-3
• Molecular Formula: C9H17NS
• Mol file: 10435-91-3.mol

Synonyms:

Chemical Property of Thiocyanic acid, 1-methylheptyl ester, (R)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Thiocyanic acid, 1-methylheptyl ester, (R)-

There total 10 articles about Thiocyanic acid, 1-methylheptyl ester, (R)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

rac-octan-2-ol (4128-31-8,113301-48-7,4128-32-9) + ammonium thiocyanate (1147550-11-5) → 2-octyl thiocyanate (10435-90-2,10435-91-3,73522-28-8,69891-64-1) + 2-isothiocyanatooctane (21663-52-5,69626-80-8)

Guidance literature:

With bromine; triphenylphosphine; In acetonitrile; at 20 ℃;

DOI:10.1039/a906113d

Reference yield:

trimethyl-(1-methyl-heptyloxy)-silane (18023-52-4) + ammonium thiocyanate (1147550-11-5) → 2-octyl thiocyanate (10435-90-2,10435-91-3,73522-28-8,69891-64-1) + 2-isothiocyanatooctane (21663-52-5,69626-80-8)

Guidance literature:

ammonium thiocyanate; With 4-aminophenyl diphenylphosphinite; bromine; In acetonitrile; at 20 ℃; for 2h;

trimethyl-(1-methyl-heptyloxy)-silane; In acetonitrile; at 20 ℃; for 0.0833333h;

DOI:10.1080/10426500802417950

Reference yield:

rac-octan-2-ol (4128-31-8,113301-48-7,4128-32-9) + tetrabutylammonium thiocyanate (3674-54-2) → 2-octyl thiocyanate (10435-90-2,10435-91-3,73522-28-8,69891-64-1) + 2-isothiocyanatooctane (21663-52-5,69626-80-8)

Guidance literature:

With triphenylphosphine; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In acetonitrile; at 20 ℃; for 0.25h;

DOI:10.1016/j.tet.2006.03.030

upstream raw materials:

rac-octan-2-ol

ammonium thiocyanate

C₁₄H₂₁O₃P

sodium thiocyanide