18023-52-4Relevant articles and documents
Mild, Effective and Selective Method for the Silylation of Alcohols Using Silazanes Promoted by Catalytic Tetrabutylammonium Fluoride
Tanabe, Yoo,Murakami, Masanari,Kitaichi, Kazuto,Yoshida, Yoshihiro
, p. 8409 - 8412 (1994)
The presence of catalytic amounts (ca. 0.02 equiv.) of tetrabutylammonium fluoride (TBAF) significantly promoted the silylation of alcohols using a variety of available silazanes under mild conditions with high chemoselectivity, wherein the choice of sila
Room temperature silylation of alcohols catalyzed by metal organic frameworks
Dhakshinamoorthy, Amarajothi,Santiago-Portillo, Andrea,Concepción, Patricia,Herance, José R.,Navalón, Sergio,Alvaro, Mercedes,Garcia, Hermenegildo
, p. 2445 - 2449 (2017/07/24)
The commercial Al(OH)(BDC) (BDC: 1,4-benzenedicarboxylic acid) metal organic framework (Basolite A100) is a suitable heterogeneous catalyst for the silylation of benzylic and aliphatic alcohols by hexamethyldisilazane in toluene at room temperature. Al(OH
Selective silylation of alcohols, phenols and oximes using N-chlorosaccharin as an efficient catalyst under mild and solvent-free conditions
Aghapour, Ghasem,Moghaddam, Ali Kazemi,Nadali, Samaneh
, p. 197 - 203 (2015/05/12)
Efficient silylation of OH group in alcohols, phenols and oximes is described using a catalytic amount of N-chlorosaccharin and hexamethyldisilazane (HMDS) under mild and solvent-free conditions. This silylation reaction can be carried out with excellent and interesting various selectivities.