(Dodec-1-en-2-yl)(triphenyl)stannane

Base Information

Chemical Name:(Dodec-1-en-2-yl)(triphenyl)stannane
CAS No.:104849-57-2
Molecular Formula:C₃₀H₃₈Sn
Molecular Weight:517.342
Hs Code.:
DSSTox Substance ID:DTXSID00547223
Wikidata:Q82425309
Mol file:104849-57-2.mol

Synonyms:104849-57-2;(Dodec-1-en-2-yl)(triphenyl)stannane;DTXSID00547223

Suppliers and Price of (Dodec-1-en-2-yl)(triphenyl)stannane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemical Property of (Dodec-1-en-2-yl)(triphenyl)stannane

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:13
Exact Mass:518.199554
Heavy Atom Count:31
Complexity:431

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCCCCCCCCCC(=C)[Sn](C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3

Technology Process of (Dodec-1-en-2-yl)(triphenyl)stannane

There total 2 articles about (Dodec-1-en-2-yl)(triphenyl)stannane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 42.0%

: 765-03-7
1-dodecyne

: 892-20-6
triphenylstannane

: 104849-57-2
2-triphenylstannyl-1-dodecene

: 114566-84-6
(E)-1-triphenylstannyl-2-dodecene

: 104849-58-3,104849-71-0
(E)-1-(triphenylstannyl)-1-dodecene

: 104849-58-3,104849-71-0
(Z)-1-(triphenylstannyl)-1-dodecene

Guidance literature:: PdCl₂{P(o-MeC₆H₄)3}2; In not given; catalitic amt. of PdCl2(P(o-MeC6H4)3)2 added to soln. of acetylene and Ph3SnH at 25°C under Ar, stirred at 25°C for 6 h, poured into water; extd. with ethyl acetate, dried (Na2SO4), evapd., preparative TLC (hexane);
DOI:10.1246/bcsj.60.3468

Reference yield:

: 765-03-7
1-dodecyne

: 892-20-6
triphenylstannane

: 104849-57-2
2-triphenylstannyl-1-dodecene

: 104849-58-3,104849-71-0
(E)-1-(triphenylstannyl)-1-dodecene

: 104849-58-3,104849-71-0
(Z)-1-(triphenylstannyl)-1-dodecene

Guidance literature:: tetrakis(triphenylphosphine) palladium⁽⁰⁾; In dichloromethane; Pd(PPh3)4 added to soln. of acetylene and Ph3SnH in CH2Cl2 under Ar, stirred at 25°C for 5 h, poured into water; combined yield 77%, isomeric ratio 11:82:7; extd. with ethyl acetate, dried (Na2SO4), evapd., preparative TLC on SiO2;
DOI:10.1246/bcsj.60.3468