Benzene, 1,1'-tellurinylbis(4-methoxy-

Base Information

• Chemical Name: Benzene, 1,1'-tellurinylbis(4-methoxy-
• CAS No.: 57857-70-2
• Molecular Formula: C14H14O3Te
• Molecular Weight: 357.863
• DSSTox Substance ID: DTXSID80206568
• Nikkaji Number: J38.986B
• Wikidata: Q83080406
• Mol file: 57857-70-2.mol

Synonyms:Benzene, 1,1'-tellurinylbis(4-methoxy-;BRN 2375444;Bis(p-methoxyphenyl)oxotellurium;57857-70-2;Tellurium, bis(p-methoxyphenyl)oxo-;1,1'-Tellurinylbis(4-methoxybenzene);Bis(4-methoxyphenyl) telluroxide;1-methoxy-4-[(4-methoxyphenyl)tellurinyl]benzene;C14H14O3Te;bis-(p-methoxyphenyl)telluroxide;SCHEMBL10665021;bis-(p-methoxyphenyl)-telluroxide;C14-H14-O3-Te;DTXSID80206568;UVDGYXYOEDJRFV-UHFFFAOYSA-N;AKOS024419341;LS-32161

Chemical Property of Benzene, 1,1'-tellurinylbis(4-methoxy-

Chemical Property:

• PSA: 35.53000
• LogP: 2.49120
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 4
• Exact Mass: 360.0005170
• Heavy Atom Count: 18
• Complexity: 240

Purity/Quality:

1-METHOXY-4-[(4-METHOXYPHENYL)TELLURINYL]BENZENE Aldrich ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COC1=CC=C(C=C1)[Te](=O)C2=CC=C(C=C2)OC

Technology Process of Benzene, 1,1'-tellurinylbis(4-methoxy-

There total 14 articles about Benzene, 1,1'-tellurinylbis(4-methoxy- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

bis(4-methoxyphenyl)telluride (4456-34-2) → di-(p-methoxyphenyl)tellurium oxide (57857-70-2)

Guidance literature:

With oxygen; rose bengal; In ethanol; at 20 ℃; for 1h; Irradiation;

DOI:10.1039/b403683b

Reference yield: 99.0%

Cumene hydroperoxide (80-15-9) + bis(4-methoxyphenyl)telluride (4456-34-2) → 1-methyl-1-phenylethyl alcohol (617-94-7) + di-(p-methoxyphenyl)tellurium oxide (57857-70-2)

Guidance literature:

In pyridine; for 0.166667h; Product distribution; Ambient temperature; dependence from educt ratio, addition of AcOH;

DOI:10.1016/0040-4039(90)80156-G

Reference yield: 91.0%

→ di-(p-methoxyphenyl)tellurium oxide (57857-70-2)

Guidance literature:

With potassium hydroxide; at 100 ℃;

upstream raw materials:

bis(4-methoxyphenyl)telluride

Cumene hydroperoxide

Te,Te-di(p-methoxyphenyl)-N-(p-tolylsulfonyl)tellurimide

4-nitrobenzaldehdye

Downstream raw materials:

L-cystine

bis(4-methoxyphenyl)telluride

bis [4-(N,N-dimethylamino)phenyl] telluride

p-dimethylaminophenyl(p-methoxyphenyl)tellurium(II)

Refernces

• 1、 Rajeswari,Lumb, Anshika,Khurana, Jitender M.. "The highly selective metal-free oxidation of sulfides, tellurides and phosphines using sodium bromate in the presence of recyclable ionic liquid [bmim]HSO4, at 80°C". . p. 442 - 444. Retrieved 2016/07/21.
• 2、 Oba, Makoto,Tanaka, Kazuhito,Nishiyama, Kozaburo,Ando, Wataru. "Aerobic oxidation of thiols to disulfides catalyzed by diaryl tellurides under photosensitized conditions". scheme or table. p. 4173 - 4177. Retrieved 2011/06/26.