Bicyclo[2.2.1]hept-5-ene-2-carboxylic acid, ethyl ester, (1S,2S,4S)-

Base Information

Chemical Name:Bicyclo[2.2.1]hept-5-ene-2-carboxylic acid, ethyl ester, (1S,2S,4S)-
CAS No.:105367-96-2
Molecular Formula:C₁₀H₁₄O₂
Molecular Weight:166.22
Hs Code.:
Mol file:105367-96-2.mol

Synonyms:Bicyclo[2.2.1]hept-5-ene-2-carboxylic acid,ethyl ester,(1S,2S,4S);

Suppliers and Price of Bicyclo[2.2.1]hept-5-ene-2-carboxylic acid, ethyl ester, (1S,2S,4S)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Bicyclo[2.2.1]hept-5-ene-2-carboxylic acid, ethyl ester, (1S,2S,4S)-

Chemical Property:

PSA：26.30000
LogP:1.76170

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Bicyclo[2.2.1]hept-5-ene-2-carboxylic acid, ethyl ester, (1S,2S,4S)-

There total 13 articles about Bicyclo[2.2.1]hept-5-ene-2-carboxylic acid, ethyl ester, (1S,2S,4S)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 48.0%

: C₁₄H₂₃O₅P

: 95-12-5,13360-81-1,15507-06-9,42070-72-4,67505-46-8,67671-05-0,67671-06-1,69831-10-3,42070-82-6
(-)-(1S,2S,4S)-bicyclo[2.2.1]hept-5-en-2-yl methanol

: 10138-32-6,51789-92-5,51789-95-8,105367-96-2
ethyl bicyclo[2.2.1]hept-5-ene-2-carboxylate

Guidance literature:: With lithium aluminium tetrahydride; In tetrahydrofuran; dichloromethane; at 0 - 20 ℃; for 3h; Cooling with ice; Inert atmosphere;
DOI:10.1055/s-0031-1290485

Reference yield: 23.0%

: C₁₄H₂₃O₅P

: 10138-32-6,51789-92-5,51789-95-8,105367-96-2
ethyl bicyclo[2.2.1]hept-5-ene-2-carboxylate

Guidance literature:: With lithium aluminium tetrahydride; In tetrahydrofuran; dichloromethane; at 0 - 20 ℃; for 3h; Cooling with ice; Inert atmosphere;
DOI:10.1055/s-0031-1290485

Reference yield:

: 542-92-7,25568-84-7,7313-32-8
cyclopenta-1,3-diene

: 140-88-5,9003-32-1
ethyl acrylate

: 10138-32-6,51789-92-5,51789-95-8,105367-96-2
ethyl bicyclo[2.2.1]hept-5-ene-2-carboxylate

: ethyl (1R,2R,4R)-bicyclo[2.2.1]hept-5-ene-2-carboxylate.

Guidance literature:: With chiral oxazaborolidine; tin(IV) chloride; In dichloromethane; at -78 ℃; for 16h; Title compound not separated from byproducts;
DOI:10.1002/anie.200461319