Bicyclo[2.2.1]hept-5-ene-2-methanol

Base Information Edit

Chemical Name:Bicyclo[2.2.1]hept-5-ene-2-methanol
CAS No.:95-12-5
Molecular Formula:C8H12O
Molecular Weight:124.183
Hs Code.:2906199090
European Community (EC) Number:202-392-0,802-773-7
NSC Number:403110
DSSTox Substance ID:DTXSID3038698
Nikkaji Number:J21.816B
Mol file:95-12-5.mol

Synonyms:5-norbornene-2-methanol

Suppliers and Price of Bicyclo[2.2.1]hept-5-ene-2-methanol

Supply Marketing:Edit

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
Bicyclo[2.2.1]hept-5-en-2-ylmethanol
500mg
$ 75.00

TRC
Bicyclo[2.2.1]hept-5-en-2-ylmethanol
100mg
$ 60.00

TCI Chemical
5-Norbornen-2-methanol (mixture of isomers) >98.0%(GC)
25g
$ 146.00

TCI Chemical
5-Norbornen-2-methanol (mixture of isomers) >98.0%(GC)
5g
$ 45.00

SynQuest Laboratories
5-Norbornene-2-yl methanol
5 g
$ 35.00

SynQuest Laboratories
5-Norbornene-2-yl methanol
1 g
$ 20.00

SynQuest Laboratories
5-Norbornene-2-yl methanol
25 g
$ 115.00

Sigma-Aldrich
5-Norbornene-2-methanol 98%, mixture of endo and exo
5g
$ 109.00

Matrix Scientific
5-Norbornene-2-methanol
25g
$ 72.00

Matrix Scientific
5-Norbornene-2-methanol
500g
$ 488.00

Total 62 raw suppliers

Chemical Property of Bicyclo[2.2.1]hept-5-ene-2-methanol Edit

Chemical Property:

Vapor Pressure:0.158mmHg at 25°C
Refractive Index:n20/D 1.500(lit.)
Boiling Point:189.2 °C at 760 mmHg
PKA:14.92±0.10(Predicted)
Flash Point:81.6 °C
PSA：20.23000
Density:1.061 g/cm³
LogP:1.19090
Storage Temp.:Keep in dark place,Sealed in dry,Room Temperature
XLogP3:1.2
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:1
Exact Mass:124.088815002
Heavy Atom Count:9
Complexity:140

Purity/Quality:

99.0%min ^*data from raw suppliers

Bicyclo[2.2.1]hept-5-en-2-ylmethanol ^*data from reagent suppliers

Safty Information:

Pictogram(s): Xn
Hazard Codes:Xn
Statements: 20/21/22
Safety Statements: 36/37/39-45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Canonical SMILES:C1C2CC(C1C=C2)CO
Uses Monomer for the modification of condensation and addition polymers for coatings. 5-Norbornene-2-methanol has been used in the preparation of:4-(norborn-2-ene-5-ylmethyleneoxy)-2,2′:6′,2′′-terpyridine5- {[(3,5-di-t-butyl-4-hydroxy-benzoyl)oxy]methyl}-2-norbornene (BHBN)

Technology Process of Bicyclo[2.2.1]hept-5-ene-2-methanol

There total 101 articles about Bicyclo[2.2.1]hept-5-ene-2-methanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 5453-80-5,19926-90-0
5-Norbornene-2-carboxaldehyde

: 95-12-5
5-hydroxymethyl-2-norbornene

Guidance literature:: 5-Norbornene-2-carboxaldehyde; With sodium tetrahydroborate; at 25 ℃; for 0.333333h; Ball milling; neat (no solvent);

With water; regiospecific reaction;
DOI:10.1002/ejoc.200900352

Reference yield: 96.0%

: 934-30-5,1195-12-6,20507-53-3,58001-99-3,67999-50-2,67999-53-5,74645-32-2,108266-75-7,120-74-1
5-norbornene-endo-2-carboxylic acid

: 95-12-5
5-hydroxymethyl-2-norbornene

Guidance literature:: With lithium aluminium tetrahydride; In tetrahydrofuran; Cooling;
DOI:10.1021/jacs.8b03979

Reference yield: 83.0%

: 5-Benzyloxymethyl-bicyclo[2.2.1]hept-2-ene

: 95-12-5
5-hydroxymethyl-2-norbornene

Guidance literature:: 5-Benzyloxymethyl-bicyclo[2.2.1]hept-2-ene; With isocyanate de chlorosulfonyle; sodium carbonate; In dichloromethane; for 20h; Heating;

With sodium hydroxide; In methanol; at 20 ℃; for 1h;
DOI:10.1016/S0040-4039(02)02648-5