[Dimethyl[(1E)-1-methyl-2-phenylethenyl]silyl]benzene

Base Information

• Chemical Name: [Dimethyl[(1E)-1-methyl-2-phenylethenyl]silyl]benzene
• CAS No.: 106621-01-6
• Molecular Formula: C17H20Si
• Molecular Weight: 252.431
• DSSTox Substance ID: DTXSID901213140
• Nikkaji Number: J2.724.215D,J2.820.370E
• Mol file: 106621-01-6.mol

Synonyms:DTXSID901213140;106621-01-6;[Dimethyl[(1E)-1-methyl-2-phenylethenyl]silyl]benzene

Chemical Property of [Dimethyl[(1E)-1-methyl-2-phenylethenyl]silyl]benzene

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 3
• Exact Mass: 252.133427172
• Heavy Atom Count: 18
• Complexity: 278

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=CC1=CC=CC=C1)[Si](C)(C)C2=CC=CC=C2
• Isomeric SMILES: C/C(=C\C1=CC=CC=C1)/[Si](C)(C)C2=CC=CC=C2

Technology Process of [Dimethyl[(1E)-1-methyl-2-phenylethenyl]silyl]benzene

There total 10 articles about [Dimethyl[(1E)-1-methyl-2-phenylethenyl]silyl]benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

1-phenylpropadiene (2327-99-3) → (E)-(1-(4-fluorophenyl)prop-1-en-2-yl)dimethyl(phenyl)silane (106621-01-6)

Guidance literature:

With ammonium chloride; 1.) THF, -78 deg C, 1 h, 2.) MeOH, -78 deg C;

DOI:10.1039/c39860001010

Reference yield:

1-Phenylprop-1-yne (673-32-5) + carbon monoxide (201230-82-2) + Dimethylphenylsilane (766-77-8) → (E)-(1-(4-fluorophenyl)prop-1-en-2-yl)dimethyl(phenyl)silane (106621-01-6) + (Z)-2-methyl-3-phenyl-3-(dimethylphenylsilyl)-propenal (119481-13-9) + (Z)-2-phenyl-3-(dimethylphenylsilyl)-2-butenal (145491-08-3) + (E)-dimethyl(phenyl)(1-phenylprop-1-en-1-yl)silane

Guidance literature:

With [Rh₂(MeCN)2(Naft)4](BF₄)4; In dichloromethane; at 100 ℃; for 24h; under 22801.5 Torr; optical yield given as %de; chemoselective reaction; Autoclave;

DOI:10.1016/j.jorganchem.2009.12.018

Reference yield:

1-Phenylprop-1-yne (673-32-5) + carbon monoxide (201230-82-2) + Dimethylphenylsilane (766-77-8) → (E)-(1-(4-fluorophenyl)prop-1-en-2-yl)dimethyl(phenyl)silane (106621-01-6) + (Z)-2-phenyl-3-(dimethylphenylsilyl)-2-butenal (145491-08-3) + (E)-dimethyl(phenyl)(1-phenylprop-1-en-1-yl)silane

Guidance literature:

With dodecacarbonyltetrarhodium⁽⁰⁾; In toluene; at 100 ℃; for 24h; under 22801.5 Torr; optical yield given as %de; Autoclave;

DOI:10.1016/j.jorganchem.2009.12.018

upstream raw materials:

1-phenylpropadiene

1-Phenylprop-1-yne

carbon monoxide

Dimethylphenylsilane