Silane, (3-cyclohexen-1-yloxy)(1,1-dimethylethyl)dimethyl-

Base Information

• Chemical Name: Silane, (3-cyclohexen-1-yloxy)(1,1-dimethylethyl)dimethyl-
• CAS No.: 106810-75-7
• Molecular Formula: C12H24OSi
• Molecular Weight: 212.407
• DSSTox Substance ID: DTXSID50546802
• Nikkaji Number: J305.626K
• Mol file: 106810-75-7.mol

Synonyms:106810-75-7;Silane, (3-cyclohexen-1-yloxy)(1,1-dimethylethyl)dimethyl-;tert-butyl-cyclohex-3-en-1-yloxy-dimethylsilane;tert-Butyl[(cyclohex-3-en-1-yl)oxy]dimethylsilane;SCHEMBL3868726;DTXSID50546802;WLZ3141;SXXWUOABOQVPGK-UHFFFAOYSA-N;tert-butyl(cyclohex-3-en-1-yloxy)dimethylsilane

Chemical Property of Silane, (3-cyclohexen-1-yloxy)(1,1-dimethylethyl)dimethyl-

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 3
• Exact Mass: 212.159641919
• Heavy Atom Count: 14
• Complexity: 213

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C)(C)[Si](C)(C)OC1CCC=CC1

Technology Process of Silane, (3-cyclohexen-1-yloxy)(1,1-dimethylethyl)dimethyl-

There total 7 articles about Silane, (3-cyclohexen-1-yloxy)(1,1-dimethylethyl)dimethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

1H-imidazole (288-32-4) + tert-butyldimethylsilyl chloride (18162-48-6) + 3-cyclohexen-1-ol (822-66-2,72137-22-5) → tert-butyl (cyclohex-3-en-1-yloxy)dimethylsilane (106810-75-7)

Guidance literature:

In tetrahydrofuran; at 21 ℃; for 2h; Heating;

DOI:10.1111/j.2042-7158.1997.tb06123.x

Reference yield: 66.0%

C21H29NO5Si → tert-butyl (cyclohex-3-en-1-yloxy)dimethylsilane (106810-75-7)

Guidance literature:

With copper bis(2-ethyl hexanoate); 5,10-bis(4-(trifluoromethyl)phenyl)-5,10-dihydrophenazine; In toluene; at 20 ℃; Irradiation; Inert atmosphere;

DOI:10.1021/acscatal.7b04281

Reference yield: 57.0%

4-(tert-butyldimethylsiloxy)octa-1,7-diene → tert-butyl (cyclohex-3-en-1-yloxy)dimethylsilane (106810-75-7)

Guidance literature:

aluminum oxide; silica gel; methyltrioxorhenium(VII); In dichloromethane; Ambient temperature;

DOI:10.1016/S0040-4039(00)79212-4

upstream raw materials:

1H-imidazole

tert-butyldimethylsilyl chloride

3-cyclohexen-1-ol

1,4-Cyclohexanediol