Rhenium, trichlorooxobis[tris(4-methylphenyl)phosphine]-

Base Information

Chemical Name:Rhenium, trichlorooxobis[tris(4-methylphenyl)phosphine]-
CAS No.:108009-08-1
Molecular Formula:C₄₂H₄₂Cl₃OP₂Re
Molecular Weight:917.308
Hs Code.:
Mol file:108009-08-1.mol

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Chemical Property of Rhenium, trichlorooxobis[tris(4-methylphenyl)phosphine]-

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Technology Process of Rhenium, trichlorooxobis[tris(4-methylphenyl)phosphine]-

There total 2 articles about Rhenium, trichlorooxobis[tris(4-methylphenyl)phosphine]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 10466-65-6
potassium perrhenate

: 1038-95-5,218281-19-7
Tri(p-tolyl)phosphine

: 108009-08-1,108741-33-9
ReOCl₃(P(p-tolyl)3)2

Guidance literature:: With HCl; In ethanol; (Ar); refluxing (conc. HCl, ethanol); filtn. (70°C), washing (ethanol, water);
DOI:10.1016/0020-1693(95)04657-U

Reference yield: 85.0%

: 207984-93-8
per-rhenic acid

: 1038-95-5,218281-19-7
Tri(p-tolyl)phosphine

: 108009-08-1,108741-33-9
ReOCl₃(P(p-tolyl)3)2

Guidance literature:: With HCl; In acetic acid; aq. acetic acid; addn. of concd. HCl to HReO4, addn. of soln. to phosphine in acetic acid, stirred for 1 h at ambient temp.; filtered, washed with acetic acid and ether, dried under vac.; elem. anal.;
DOI:10.1021/ja00253a017

Reference yield: 49.0%

: 16853-85-3
lithium aluminium tetrahydride

: 108009-08-1,108741-33-9
ReOCl₃(P(p-tolyl)3)2

: 7H^(1-)*Re⁽⁷⁺⁾*2P(CH₃C₆H₄)3=H₇Re(P(CH₃C₆H₄)3)2

Guidance literature:: In diethyl ether; under N2, stirred for 1 h at ambient temp.; cooled to 0°C under N2, addn. of NaOH soln. and then water, filtered, washed with ether, concn. of filtrates, addn. of ether, chilling, pptn. filtered off, washed with ether, dried; elem. anal.;
DOI:10.1021/ja00253a017