(E)-1-[(Naphthalen-1-yl)oxy]-2-phenyldiazene

Base Information

• Chemical Name: (E)-1-[(Naphthalen-1-yl)oxy]-2-phenyldiazene
• CAS No.: 109057-65-0
• Molecular Formula: C16H12N2O
• Molecular Weight: 248.284
• DSSTox Substance ID: DTXSID50546620
• Mol file: 109057-65-0.mol

Synonyms:109057-65-0;(E)-1-[(Naphthalen-1-yl)oxy]-2-phenyldiazene;DTXSID50546620

Chemical Property of (E)-1-[(Naphthalen-1-yl)oxy]-2-phenyldiazene

Chemical Property:

• XLogP3: 5.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 3
• Exact Mass: 248.094963011
• Heavy Atom Count: 19
• Complexity: 299

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)N=NOC2=CC=CC3=CC=CC=C32

Technology Process of (E)-1-[(Naphthalen-1-yl)oxy]-2-phenyldiazene

There total 2 articles about (E)-1-[(Naphthalen-1-yl)oxy]-2-phenyldiazene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 42.0%

α-naphthol (90-15-3) + Phenyl-phenylazo-methyl-hydroperoxide; compound with benzene (104354-87-2,109577-19-7,115348-28-2) → C16H12N2O (109057-65-0) + 4-Phenylbenzaldehyde (3218-36-8) + 2-phenylazo-1-naphthol (3375-23-3) + 4-Phenylazo-1-naphthol (3651-02-3)

Guidance literature:

In neat (no solvent); Further byproducts given; Ambient temperature;

DOI:10.1246/cl.1986.1667

Reference yield: 17.0%

α-naphthol (90-15-3) + Phenyl-phenylazo-methyl-hydroperoxide; compound with benzene (104354-87-2,109577-19-7,115348-28-2) → C16H12N2O (109057-65-0) + 4-Phenylbenzaldehyde (3218-36-8) + benzoic acid (65-85-0,8013-63-6) + 2-phenylazo-1-naphthol (3375-23-3) + 4-Phenylazo-1-naphthol (3651-02-3)

Guidance literature:

In neat (no solvent); Mechanism; Product distribution; Ambient temperature;

DOI:10.1246/cl.1986.1667

Reference yield: 45.0%

C16H12N2O (109057-65-0) → biphenyl (92-52-4,1594-86-1) + α-naphthol (90-15-3)

Guidance literature:

With hydrogen; palladium on activated charcoal; In benzene;

DOI:10.1246/cl.1986.1667

upstream raw materials:

α-naphthol

Phenyl-phenylazo-methyl-hydroperoxide; compound with benzene

Downstream raw materials:

2-Bromobiphenyl

4-bromo-1,1'-biphenyl

3-bromobiphenyl

biphenyl