8-Iodo-1,1,1,2,2,3,3,4,4,5,5,6,6-tridecafluorotetradecane

Base Information

• Chemical Name: 8-Iodo-1,1,1,2,2,3,3,4,4,5,5,6,6-tridecafluorotetradecane
• CAS No.: 109574-84-7
• Molecular Formula: C14H16F13I
• Molecular Weight: 558.16100
• Hs Code.: 2903798000
• Mol file: 109574-84-7.mol

Synonyms:8-Iodo-1,1,1,2,2,3,3,4,4,5,5,6,6-tridecafluorotetradecane;2-Iodo-1-(perfluorohex-1-yl)octane;Tetradecane,1,1,1,2,2,3,3,4,4,5,5,6,6-tridecafluoro-8-iodo;2-Iodo-1-(perfluorohexyl)octane;

Chemical Property of 8-Iodo-1,1,1,2,2,3,3,4,4,5,5,6,6-tridecafluorotetradecane

Chemical Property:

• Boiling Point: 302.4±10.0 °C(Predicted)
• PSA: 0.00000
• Density: 1.595±0.06 g/cm3(Predicted)
• LogP: 7.88930

Purity/Quality:

97% ^*data from raw suppliers

2-Iodo-1-(perfluorohexyl)octane 95% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 8-Iodo-1,1,1,2,2,3,3,4,4,5,5,6,6-tridecafluorotetradecane

There total 3 articles about 8-Iodo-1,1,1,2,2,3,3,4,4,5,5,6,6-tridecafluorotetradecane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.3%

oct-1-ene (111-66-0,25068-25-1) + n-perfluorohexyl iodide (355-43-1) → 1,1,1,2,2,3,3,4,4,5,5,6,6-tridecafluoro-8-iodotetradecane (109574-84-7)

Guidance literature:

With sodiumsulfide nonahydrate; dibenzoyl peroxide; at 90 ℃; for 3h;

Reference yield: 63.0%

oct-1-ene (111-66-0,25068-25-1) + tetradecafluorohexane (355-42-0) → 1,1,1,2,2,3,3,4,4,5,5,6,6-tridecafluoro-8-iodotetradecane (109574-84-7)

Guidance literature:

With 2,2'-azobis(isobutyronitrile); at 100 ℃; for 72h;

Reference yield:

oct-1-ene (111-66-0,25068-25-1) + n-perfluorohexyl iodide (355-43-1) → 1,1,1,2,2,3,3,4,4,5,5,6,6-tridecafluoro-8-iodotetradecane (109574-84-7) + 1,1,1,2,2,3,3,4,4,5,5,6,6-tridecafluorotetradecane (133331-77-8)

Guidance literature:

With tris(bipyridine)ruthenium(II) dichloride hexahydrate; diethyl 2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate; In N,N-dimethyl-formamide; for 12h; Overall yield = 56 %; Irradiation;

upstream raw materials:

oct-1-ene

n-perfluorohexyl iodide

tetradecafluorohexane

Downstream raw materials:

1,1,1,2,2,3,3,4,4,5,5,6,6-tridecafluorotetradecane

Refernces

• 1、 Cai, Chunsheng,Wan, Ji,Zhang, Youdi,Yuan, Zhongyi,Huang, Qingfang,Xu, Guodong,Hu, Yu,Zhao, Xiaohong,Chen, Yiwang. "Semi-perfluoroalkylated perylene diimides for conjugated polymers with high molecular weight and high electron mobility". . p. 116 - 124. Retrieved 2018.
• 2、 Mao, Ting,Ma, Ming-Jian,Zhao, Liang,Xue, De-Pu,Yu, Yanbo,Gu, Jiwei,He, Chun-Yang. "A general and green fluoroalkylation reaction promoted: Via noncovalent interactions between acetone and fluoroalkyl iodides". supporting information. p. 1815 - 1818. Retrieved 2020/02/20.
• 3、 -. "MANUFACTURING METHOD OF FLUOROALKANE". Paragraph 0027. . Retrieved 2019/08/12.