Phenanthrene,7-ethenyl-1,2

Base Information

Chemical Name:Phenanthrene,7-ethenyl-1,2
CAS No.:1686-67-5
Molecular Formula:C20H32
Molecular Weight:272.474
Hs Code.:
Mol file:1686-67-5.mol

Synonyms:Phenanthrene,7-ethenyl-1,2,3,4,4a,4b,5,6,7,8,8a,9-dodecahydro-1,1,4b,7-tetramethyl-,[4aS-(4aa,4bb,7a,8aa)]-; Rimuene (6CI); Rimuen;Rosa-5,15-diene, (13S)-

Suppliers and Price of Phenanthrene,7-ethenyl-1,2

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
RIMUENE 95.00%
5MG
$ 498.23

Total 4 raw suppliers

Chemical Property of Phenanthrene,7-ethenyl-1,2

Chemical Property:

Melting Point:51-52 °C
Boiling Point:337.0±32.0 °C(Predicted)
PSA：0.00000
Density:0.93±0.1 g/cm3(Predicted)
LogP:6.14150

Purity/Quality:

99% ^*data from raw suppliers

RIMUENE 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Phenanthrene,7-ethenyl-1,2

There total 22 articles about Phenanthrene,7-ethenyl-1,2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1910-02-7
7-methoxy-4a-methyl-4,4a,9,10-tetrahydro-3H-phenanthren-2-one

: 1686-67-5,3895-07-6,10036-89-2,78821-30-4,89618-20-2,94681-67-1
(+/-)-Rimuen

Guidance literature:: Multi-step reaction with 11 steps

1: Li, liq. NH₃

2: LiAlH₄

3: Li, liq. NH₃, tBuOH

4: aq. HCl

5: (i) KOtBu, (ii) /BRN= 969135/, (iii) /BRN= 471389/, Py

6: (i) N₂H₄, (ii) NaOH, diethylene glycol, (heating)

7: CrO₃, H₂SO₄

8: (i) KOtBu, (ii) /BRN= 4138880/

9: aq. HClO₄

10: KOtBu

11: (i) nBuLi, (ii) /BRN= 4141037/

With chromium(VI) oxide; hydrogenchloride; lithium aluminium tetrahydride; perchloric acid; sulfuric acid; potassium tert-butylate; ammonia; lithium; tert-butyl alcohol;
DOI:10.1021/jo01278a041

Reference yield:

: 2685-24-7,10036-92-7,18181-48-1,58560-62-6,94372-50-6
(+/-)-7t-hydroxy-4b-methyl-(4ar,4bt,8ac)-4,4a,4b,5,6,7,8,8a,9,10-decahydro-3H-phenanthren-2-one

: 1686-67-5,3895-07-6,10036-89-2,78821-30-4,89618-20-2,94681-67-1
(+/-)-Rimuen

Guidance literature:: Multi-step reaction with 7 steps

1: (i) KOtBu, (ii) /BRN= 969135/, (iii) /BRN= 471389/, Py

2: (i) N₂H₄, (ii) NaOH, diethylene glycol, (heating)

3: CrO₃, H₂SO₄

4: (i) KOtBu, (ii) /BRN= 4138880/

5: aq. HClO₄

6: KOtBu

7: (i) nBuLi, (ii) /BRN= 4141037/

With chromium(VI) oxide; perchloric acid; sulfuric acid; potassium tert-butylate;
DOI:10.1021/jo01278a041

Reference yield:

: 1910-03-8,5655-71-0,63640-66-4,94328-99-1
(+/-)-7-methoxy-4a-methyl-(4ar,10at)-3,4,4a,9,10,10a-hexahydro-1H-phenanthren-2-one

: 1686-67-5,3895-07-6,10036-89-2,78821-30-4,89618-20-2,94681-67-1
(+/-)-Rimuen

Guidance literature:: Multi-step reaction with 10 steps

1: LiAlH₄

2: Li, liq. NH₃, tBuOH

3: aq. HCl

4: (i) KOtBu, (ii) /BRN= 969135/, (iii) /BRN= 471389/, Py

5: (i) N₂H₄, (ii) NaOH, diethylene glycol, (heating)

6: CrO₃, H₂SO₄

7: (i) KOtBu, (ii) /BRN= 4138880/

8: aq. HClO₄

9: KOtBu

10: (i) nBuLi, (ii) /BRN= 4141037/

With chromium(VI) oxide; hydrogenchloride; lithium aluminium tetrahydride; perchloric acid; sulfuric acid; potassium tert-butylate; ammonia; lithium; tert-butyl alcohol;
DOI:10.1021/jo01278a041