2,3-Diamino-7-chlorophenazine

Base Information

• Chemical Name: 2,3-Diamino-7-chlorophenazine
• CAS No.: 4559-64-2
• Molecular Formula: C₁₂H₉ClN₄
• Molecular Weight: 244.683
• Hs Code.: 2933990090
• UNII: 63LLB4X8LK
• DSSTox Substance ID: DTXSID40196557
• Nikkaji Number: J2.596.861A
• Wikidata: Q83069588
• Mol file: 4559-64-2.mol

Synonyms:2,3-Diamino-7-chlorophenazine;7-Chloro-2,3-phenazinediamine;2,3-Phenazinediamine, 7-chloro-;4559-64-2;CCRIS 3573;BRN 0384462;63LLB4X8LK;C12H9ClN4;0-25-00-00393 (Beilstein Handbook Reference);UNII-63LLB4X8LK;SCHEMBL14166725;DTXSID40196557;DIAMINO-7-CHLOROPHENAZINE, 2,3-;LS-103008

Chemical Property of 2,3-Diamino-7-chlorophenazine

Chemical Property:

• Vapor Pressure: 4.11E-11mmHg at 25°C
• Boiling Point: 524.9°Cat760mmHg
• PKA: 2.80±0.30(Predicted)
• Flash Point: 271.3°C
• PSA: 77.82000
• Density: 1.523g/cm³
• LogP: 3.76320
• XLogP3: 1.9
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 244.0515740
• Heavy Atom Count: 17
• Complexity: 288

Purity/Quality:

2,3-DIAMINO-7-CHLOROPHENAZINE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C1=CC2=C(C=C1Cl)N=C3C=C(C(=CC3=N2)N)N

Technology Process of 2,3-Diamino-7-chlorophenazine

There total 3 articles about 2,3-Diamino-7-chlorophenazine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

4-Chloro-1,2-phenylenediamine (95-83-0) → 7-chloro-phenazine-2,3-diyldiamine (4559-64-2)

Guidance literature:

With eosin y; In methanol; aq. phosphate buffer; at 20 ℃; for 12h; pH=7.2; Kinetics; Irradiation;

DOI:10.1021/acs.orglett.1c00725

Reference yield:

4-Chloro-1,2-phenylenediamine (95-83-0) → 7-chloro-phenazine-2,3-diyldiamine (4559-64-2)

Guidance literature:

With iron(III) chloride; acetic acid;

Reference yield:

4-Chloro-2-nitroaniline (89-63-4) → 7-chloro-phenazine-2,3-diyldiamine (4559-64-2)

Guidance literature:

Multi-step reaction with 2 steps

1: tin dichloride; concentrated hydrochloric acid

2: iron chloride; acetic acid

With hydrogenchloride; iron(III) chloride; acetic acid; tin(ll) chloride;

upstream raw materials:

4-Chloro-1,2-phenylenediamine

4-Chloro-2-nitroaniline

Refernces