10-(4-Chlorophenyl)phenanthren-9-OL

Base Information

Chemical Name:10-(4-Chlorophenyl)phenanthren-9-OL
CAS No.:110210-89-4
Molecular Formula:C20H13ClO
Molecular Weight:304.776
Hs Code.:
DSSTox Substance ID:DTXSID40549125
Wikidata:Q82428044

Synonyms:110210-89-4;10-(4-CHLOROPHENYL)PHENANTHREN-9-OL;DTXSID40549125

Suppliers and Price of 10-(4-Chlorophenyl)phenanthren-9-OL

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 1 raw suppliers

Chemical Property of 10-(4-Chlorophenyl)phenanthren-9-OL

Chemical Property:

XLogP3:6.3
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:1
Exact Mass:304.0654927
Heavy Atom Count:22
Complexity:376

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC=C2C(=C1)C3=CC=CC=C3C(=C2C4=CC=C(C=C4)Cl)O

Technology Process of 10-(4-Chlorophenyl)phenanthren-9-OL

There total 4 articles about 10-(4-Chlorophenyl)phenanthren-9-OL which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

: 110210-84-9
9-[Bromo-(4-chloro-phenyl)-methyl]-9H-fluoren-9-ol

: 110210-89-4
10-(4-chlorophenyl)phenanthren-9-ol

Guidance literature:: With isopropylmagnesium bromide; bis(acetylacetonate)nickel(II); In diethyl ether; benzene; at -15 ℃; for 2h;
DOI:10.1016/S0040-4039(00)85196-5

Reference yield:

: C₂₇H₂₁ClN₂O₃S

: 110210-89-4
10-(4-chlorophenyl)phenanthren-9-ol

Guidance literature:: With sodium methylate; In toluene; at 70 ℃; for 0.5h; regioselective reaction; Inert atmosphere;
DOI:10.1002/anie.201209269

Reference yield:

: 99585-64-5
(2-bromophenyl)(4-chlorophenyl)methanone

: 110210-89-4
10-(4-chlorophenyl)phenanthren-9-ol

Guidance literature:: Multi-step reaction with 3 steps

1: tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; tri tert-butylphosphoniumtetrafluoroborate; potassium fluoride dihydrate / tetrahydrofuran / 12 h / 40 °C / Inert atmosphere

2: toluene / 0.5 h / 70 °C / Inert atmosphere; Schlenk technique

3: sodium methylate / toluene / 0.5 h / 70 °C / Inert atmosphere

With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; potassium fluoride dihydrate; sodium methylate; tri tert-butylphosphoniumtetrafluoroborate; In tetrahydrofuran; toluene; 1: |Suzuki-Miyaura Coupling;
DOI:10.1002/anie.201209269