Pleraplysillin 2

Base Information

Chemical Name:Pleraplysillin 2
CAS No.:53492-34-5
Molecular Formula:C20H24O4
Molecular Weight:328.4
Hs Code.:2932190090
Nikkaji Number:J10.031E
Metabolomics Workbench ID:166953
Mol file:53492-34-5.mol

Synonyms:Pleraplysillin 2;53492-34-5;2,6-Octadienoic acid, 3,7-dimethyl-8-(4-methyl-2-furanyl)-, 3-furanylmethyl ester, (E,E)-

Suppliers and Price of Pleraplysillin 2

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 0 raw suppliers

Chemical Property of Pleraplysillin 2

Chemical Property:

Vapor Pressure:3.06E-08mmHg at 25°C
Boiling Point:448.6°C at 760 mmHg
Flash Point:225.1°C
PSA：52.58000
Density:1.081g/cm³
LogP:5.13970
XLogP3:5
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:9
Exact Mass:328.16745924
Heavy Atom Count:24
Complexity:466

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=COC(=C1)CC(=CCCC(=CC(=O)OCC2=COC=C2)C)C
Isomeric SMILES:CC1=COC(=C1)C/C(=C/CC/C(=C/C(=O)OCC2=COC=C2)/C)/C

Technology Process of Pleraplysillin 2

There total 14 articles about Pleraplysillin 2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 78284-85-2
marislin

: 53492-34-5
pleraplysillin-2

Guidance literature:: With boron trifluoride diethyl etherate; In diethyl ether;
DOI:10.1016/0040-4039(81)80073-1

Reference yield:

: 6141-57-7
methyl 3-methylfuran-2-carboxylate

: 53492-34-5
pleraplysillin-2

Guidance literature:: Multi-step reaction with 9 steps

1: Br₂

2: 1.) Br₂, 2.) KOH, H₂O / 2.) methanol, room temperature, overnight

3: 2.5 g / Cu / quinoline / 1.5 h / 260 °C / distillation apparatus, fraction at 120-160 deg C

4: 1.) n-butyl-lithium / 1.) hexane, THF, -78 deg C; 2.) below -60 deg C, 6 h, then warmed to room temperature during 2 h

5: 0.12 g / toluene-p-sulphonic acid / methanol / 16 h / Ambient temperature

6: 0.10 g / MnO₂ / hexane / 3 h / Ambient temperature

7: 0.075 g / NaCN, glacial AcOH, MnO₂ / 16 h / Ambient temperature

8: 0.045 g / H₂O, KOH / methanol / 3 h / 50 °C

9: 0.025 g / 4-dimethylaminopyridine, NN'-dicyclohexylcarbodiimide / CH₂Cl₂ / 3 h

With dmap; manganese(IV) oxide; potassium hydroxide; n-butyllithium; sodium cyanide; water; bromine; copper; toluene-4-sulfonic acid; acetic acid; dicyclohexyl-carbodiimide; In quinoline; methanol; hexane; dichloromethane;
DOI:10.1039/P19810000679

Reference yield:

: 59632-99-4
geranyl 2-tetrahydropyranyl ether

: 53492-34-5
pleraplysillin-2

Guidance literature:: Multi-step reaction with 8 steps

1: 1.) SeO₂, 2.) NaBH₄ / 1.) EtOH, pyridine, reflux, 17 h, 2.) EtOH, room temperature, 3 h

2: 0.53 g / N-bromosuccinimide, dimethyl sulphide / CH₂Cl₂ / 3.75 h / Ambient temperature

3: 1.) n-butyl-lithium / 1.) hexane, THF, -78 deg C; 2.) below -60 deg C, 6 h, then warmed to room temperature during 2 h

4: 0.12 g / toluene-p-sulphonic acid / methanol / 16 h / Ambient temperature

5: 0.10 g / MnO₂ / hexane / 3 h / Ambient temperature

6: 0.075 g / NaCN, glacial AcOH, MnO₂ / 16 h / Ambient temperature

7: 0.045 g / H₂O, KOH / methanol / 3 h / 50 °C

8: 0.025 g / 4-dimethylaminopyridine, NN'-dicyclohexylcarbodiimide / CH₂Cl₂ / 3 h

With dmap; manganese(IV) oxide; potassium hydroxide; sodium tetrahydroborate; N-Bromosuccinimide; n-butyllithium; selenium(IV) oxide; dimethylsulfide; sodium cyanide; water; toluene-4-sulfonic acid; acetic acid; dicyclohexyl-carbodiimide; In methanol; hexane; dichloromethane;
DOI:10.1039/P19810000679