Phosphorochloridothioic acid, O,O-dipropyl ester

Base Information

• Chemical Name: Phosphorochloridothioic acid, O,O-dipropyl ester
• CAS No.: 2524-05-2
• Molecular Formula: C6H14 Cl O2 P S
• Molecular Weight: 216.669
• Hs Code.: 2931900090
• European Community (EC) Number: 219-757-5
• NSC Number: 82346
• DSSTox Substance ID: DTXSID9062487
• Nikkaji Number: J192.009J
• Wikidata: Q81990067
• Mol file: 2524-05-2.mol

Synonyms:2524-05-2;O,O-Dipropyl chlorothiophosphate;O,O-Dipropyl phosphorochloridothioate;Phosphorochloridothioic acid, O,O-dipropyl ester;chloro-dipropoxy-sulfanylidene-lambda5-phosphane;O,O-Dipropyl chlorothiophosphonate;O,O-Dipropyl thionophosphorochloridate;O,O-DIPROPYL CHLOROPHOSPHONOTHIOATE;Dipropyl chlorothiophosphate;di-n-propylchlorothiophosphate;SCHEMBL2150777;DTXSID9062487;O,O-dipropyl chloridothiophosphate;NSC82346;EINECS 219-757-5;NSC 82346;NSC-82346;AKOS024332391;Chloridothiophosphoric acid dipropyl ester;Phosphorochloridothioic acid,O-dipropyl ester

Chemical Property of Phosphorochloridothioic acid, O,O-dipropyl ester

Chemical Property:

• Vapor Pressure: 0.0551mmHg at 25°C
• Boiling Point: 241.6°Cat760mmHg
• Flash Point: 99.9°C
• PSA: 60.36000
• Density: 1.179g/cm³
• LogP: 3.95350
• XLogP3: 3.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 6
• Exact Mass: 216.0140656
• Heavy Atom Count: 11
• Complexity: 131

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCOP(=S)(OCCC)Cl

Technology Process of Phosphorochloridothioic acid, O,O-dipropyl ester

There total 9 articles about Phosphorochloridothioic acid, O,O-dipropyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

propan-1-ol (71-23-8) → O,O-dipropyl chlorothiophosphate (2524-05-2)

Guidance literature:

With trichlorothiophosphine; at -10 - -5 ℃; for 2h;

Reference yield: 68.3%

dipropyl thiophosphite (14609-96-2) → O,O-dipropyl chlorothiophosphate (2524-05-2)

Guidance literature:

With sulfuryl dichloride; In benzene; for 0.5h;

Reference yield:

O.O-Dipropyl-dithyophosphat (2253-43-2,69941-00-0) → O,O-dipropyl chlorothiophosphate (2524-05-2)

Guidance literature:

With hydrogenchloride; benzyl thiocyanate; In diethyl ether;

DOI:10.1021/jo01081a043

upstream raw materials:

propan-1-ol

O-propyl thiophosphorodichloridate

O_.O-Dipropyl-dithyophosphat

O,O,O-tripropyl phosphorothioate

Downstream raw materials:

potassium O,O-dipropyl phosphorothioate

Thiophosphorsaeure-diisopropylester-pentachlorphenylester

Thiophosphoric acid O,O'-dipropyl ester O''-[2,2,2-trichloro-1-(3-phenoxy-phenyl)-ethyl] ester

Thiophosphoric acid O-[cyano-(3-phenoxy-phenyl)-methyl] ester O',O''-dipropyl ester

Refernces

• 1、 Gupta, Arvind K.,Dubey,Parashar,Kaushik. "An efficient synthesis of O,O- di propyl (E)-2-[1-methyl 2-oxopropylidene]phosphorohydrazidothiolate (E) oxime and its analogues: A potential marine toxin". scheme or table. p. 1892 - 1910. Retrieved 2009/08/07.
• 2、 Zabirov, N. G.,Cherkasov, R. A.,Khalikov, I. S.,Pudovik, A. N.. "LAWESSON'S REAGENT IN ORGANOPHOSPHORUS SYNTHESIS. III. TRANSFORMATION OF DIALKYLPHOSPHOROUS ACIDS INTO DIALKYLTHIOPHOSPHOROUS ACIDS AND DIALKYLCHLOROTHIOPHOSPHATES". . p. 1327 - 1332. Retrieved 2007/10/02.