3,3'-Dimethoxyazobenzene

Base Information

• Chemical Name: 3,3'-Dimethoxyazobenzene
• CAS No.: 6319-23-9
• Molecular Formula: C14H14N2O2
• Molecular Weight: 242.277
• NSC Number: 31010
• Nikkaji Number: J1.027.668C
• Mol file: 6319-23-9.mol

Synonyms:3,3'-DIMETHOXYAZOBENZENE;NSC 31010;6319-23-9;NSC31010;SCHEMBL10818541;SCHEMBL17707284;NSC-31010

Chemical Property of 3,3'-Dimethoxyazobenzene

Chemical Property:

• Vapor Pressure: 4.56E-06mmHg at 25°C
• Boiling Point: 394.3°C at 760 mmHg
• Flash Point: 155.5°C
• Density: 1.09g/cm³
• XLogP3: 3.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 4
• Exact Mass: 242.105527694
• Heavy Atom Count: 18
• Complexity: 245

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COC1=CC=CC(=C1)N=NC2=CC(=CC=C2)OC

Technology Process of 3,3'-Dimethoxyazobenzene

There total 18 articles about 3,3'-Dimethoxyazobenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

m-Anisidine (536-90-3,918666-97-4) → 1,2-bis(3-methoxyphenyl)diazene (6319-23-9)

Guidance literature:

With copper-manganese spinel oxide; In ethyl acetate; at 80 ℃; for 5h;

DOI:10.1002/cctc.201501218

Reference yield: 95.0%

3-nitroanisole (555-03-3) → 1,2-bis(3-methoxyphenyl)diazene (6319-23-9)

Guidance literature:

With chloro-trimethyl-silane; samarium diiodide; tetra-(n-butyl)ammonium iodide; tert-butylammonium hexafluorophosphate(V); In tetrahydrofuran; at 20 ℃; for 5h; Electrochemical reaction;

DOI:10.1021/acscatal.7b02940

Reference yield: 89.0%

3-nitroanisole (555-03-3) → (E)-1,2-bis(3-methoxyphenyl)diazene (6319-23-9)

Guidance literature:

With ammonium acetate; lead; In methanol; at 20 ℃;

DOI:10.1081/SCC-120026850

upstream raw materials:

3-nitroanisole

3,3'-bis(methoxy)diphenyl hydrazine

bis-(3-methoxy-phenyl)-diazene-N-oxide

m-Anisidine

Downstream raw materials:

3,3'-bis(methoxy)diphenyl hydrazine

1,2,4,5-Tetra-m-anisyl-3,3,6,6-tetramethyl-1,2,4,5-tetraaza-3,6-disila-cyclohexan

1.2.4.5-Tetra-m-anisyl-3.3.6.6-tetraphenyl-1.2.4.5-tetraaza-3.6-disila-cyclohexan

m-Anisidine