1,2-Benzenediol, monoformate

Base Information

Chemical Name:1,2-Benzenediol, monoformate
CAS No.:110851-12-2
Molecular Formula:C7H6O3
Molecular Weight:138.123
Hs Code.:
Mol file:110851-12-2.mol

Synonyms:(2-Hydroxy-phenyl)-formiat;1,2-Benzenediol,monoformate;2-Hydroxy-1-formyloxy-benzol;2-Formyloxy-phenol;catechol monoformate;Ameisensaeure-(2-hydroxy-phenylester);O-Formyl-brenzcatechin;

Suppliers and Price of 1,2-Benzenediol, monoformate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1,2-Benzenediol, monoformate

Chemical Property:

Boiling Point:125 °C(Press: 12 Torr)
PSA：77.76000
Density:1.265±0.06 g/cm3(Predicted)
LogP:1.43450

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 1,2-Benzenediol, monoformate

There total 10 articles about 1,2-Benzenediol, monoformate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 4.5%

: 1864-94-4
phenyl formate

: 89683-20-5
4-hydroxyphenyl formate

: 110851-12-2
catechol monoformate

: 120-80-9,19481-10-8,37349-32-9
benzene-1,2-diol

: 89683-19-2
formyl resorcinol

: 108-95-2,27073-41-2
phenol

Guidance literature:: With dihydrogen peroxide; at -20 ℃; for 0.5h; Product distribution; HF - SbF₅; relative proportion;

Reference yield:

: 255-37-8
benzo[1,4]dioxine

: 110851-12-2
catechol monoformate

: 120-80-9,19481-10-8,37349-32-9
benzene-1,2-diol

Guidance literature:: With ozone; trifluoroacetic acid; Yield given. Multistep reaction. Yields of byproduct given; 1.) CH₂Cl₂, -78 deg C, 2.) CH₂Cl₂, -78 deg C, 3 h;
DOI:10.1021/jo00234a020

Reference yield:

: 120-80-9,19481-10-8,37349-32-9
benzene-1,2-diol

: 110851-12-2
catechol monoformate

Guidance literature:: Multi-step reaction with 3 steps

1: potassium carbonate / ethane-1,2-diol / 4 h / 120 °C

2: 1.) N-bromosuccinimide (NBS), AIBN, 2.) NaI / 1.) carbon tetrachloride, 12 h, reflux, 2.) acetone, 2 h, reflux

3: 1.) O₃, 2.)trifluoroacetic acid / 1.) CH₂Cl₂, -78 deg C, 2.) CH₂Cl₂, -78 deg C, 3 h

With N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile); potassium carbonate; ozone; trifluoroacetic acid; sodium iodide; In ethylene glycol;
DOI:10.1021/jo00234a020