Benzene, [[(2-ethyl-4-pentenyl)oxy]methyl]-, (R)-

Base Information

Chemical Name:Benzene, [[(2-ethyl-4-pentenyl)oxy]methyl]-, (R)-
CAS No.:111456-66-7
Molecular Formula:C14H20O
Molecular Weight:204.312
Hs Code.:

Synonyms:

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Chemical Property of Benzene, [[(2-ethyl-4-pentenyl)oxy]methyl]-, (R)-

Chemical Property:

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Technology Process of Benzene, [[(2-ethyl-4-pentenyl)oxy]methyl]-, (R)-

There total 9 articles about Benzene, [[(2-ethyl-4-pentenyl)oxy]methyl]-, (R)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 73574-05-7
(2S,1'S)-2-(1-hydroxyethyl)-pent-4-enoate d'ethyle

: 111456-66-7
(R)-4-<(benzyloxy)methyl>-1-hexene

Guidance literature:: Multi-step reaction with 6 steps

1: pyridinium p-toluenesulfonate / CH₂Cl₂

2: 99.7 percent / LAH / diethyl ether

3: 59.7 g / NaH 60 percent , n-Bu₄N⁽¹⁺⁾*I^(1-) / paraffin; tetrahydrofuran / 3 h / Heating

4: p-TsOH*H₂O / methanol

5: DMAP / pyridine

6: 1.) LiBEt₃H, 2.) 3 N NaOH aq., 35 percent H₂O₂ aq. / 1.) THF, -5 deg C, then reflux, 20 min, 2.) H₂O, 50 deg C, then 30 min, room temperature

With dmap; sodium hydroxide; lithium aluminium tetrahydride; dihydrogen peroxide; tetra-(n-butyl)ammonium iodide; sodium hydride; lithium triethylborohydride; pyridinium p-toluenesulfonate; toluene-4-sulfonic acid; In tetrahydrofuran; pyridine; methanol; diethyl ether; dichloromethane; paraffin;
DOI:10.1016/S0040-4020(01)89929-4

Reference yield:

: 113195-22-5
(2R,3S)-2-allylbutane-1,3-diol 3-THP ether

: 111456-66-7
(R)-4-<(benzyloxy)methyl>-1-hexene

Guidance literature:: Multi-step reaction with 4 steps

1: 59.7 g / NaH 60 percent , n-Bu₄N⁽¹⁺⁾*I^(1-) / paraffin; tetrahydrofuran / 3 h / Heating

2: p-TsOH*H₂O / methanol

3: DMAP / pyridine

4: 1.) LiBEt₃H, 2.) 3 N NaOH aq., 35 percent H₂O₂ aq. / 1.) THF, -5 deg C, then reflux, 20 min, 2.) H₂O, 50 deg C, then 30 min, room temperature

With dmap; sodium hydroxide; dihydrogen peroxide; tetra-(n-butyl)ammonium iodide; sodium hydride; lithium triethylborohydride; toluene-4-sulfonic acid; In tetrahydrofuran; pyridine; methanol; paraffin;
DOI:10.1016/S0040-4020(01)89929-4

Reference yield:

: 113195-21-4
ethyl (2S,1'S)-2-(1'-tetrahydropyranyloxyethyl)pent-4-enoate

: 111456-66-7
(R)-4-<(benzyloxy)methyl>-1-hexene

Guidance literature:: Multi-step reaction with 5 steps

1: 99.7 percent / LAH / diethyl ether

2: 59.7 g / NaH 60 percent , n-Bu₄N⁽¹⁺⁾*I^(1-) / paraffin; tetrahydrofuran / 3 h / Heating

3: p-TsOH*H₂O / methanol

4: DMAP / pyridine

5: 1.) LiBEt₃H, 2.) 3 N NaOH aq., 35 percent H₂O₂ aq. / 1.) THF, -5 deg C, then reflux, 20 min, 2.) H₂O, 50 deg C, then 30 min, room temperature

With dmap; sodium hydroxide; lithium aluminium tetrahydride; dihydrogen peroxide; tetra-(n-butyl)ammonium iodide; sodium hydride; lithium triethylborohydride; toluene-4-sulfonic acid; In tetrahydrofuran; pyridine; methanol; diethyl ether; paraffin;
DOI:10.1016/S0040-4020(01)89929-4