Carbamic acid, [6-(chlorocarbonyl)-2-methoxy-1,2-oxaphosphorinan-3-yl]-, phenylmethyl ester, P-oxide

Base Information

Chemical Name:Carbamic acid, [6-(chlorocarbonyl)-2-methoxy-1,2-oxaphosphorinan-3-yl]-, phenylmethyl ester, P-oxide
CAS No.:111603-41-9
Molecular Formula:C₁₄H₁₇ClNO₆P
Molecular Weight:361.719
Hs Code.:
Mol file:111603-41-9.mol

Synonyms:

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Chemical Property of Carbamic acid, [6-(chlorocarbonyl)-2-methoxy-1,2-oxaphosphorinan-3-yl]-, phenylmethyl ester, P-oxide

Chemical Property:

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Technology Process of Carbamic acid, [6-(chlorocarbonyl)-2-methoxy-1,2-oxaphosphorinan-3-yl]-, phenylmethyl ester, P-oxide

There total 8 articles about Carbamic acid, [6-(chlorocarbonyl)-2-methoxy-1,2-oxaphosphorinan-3-yl]-, phenylmethyl ester, P-oxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 2100-17-6
4-pentenal

: 111603-41-9
(6-Chlorocarbonyl-2-methoxy-2-oxo-2λ⁵-[1,2]oxaphosphinan-3-yl)-carbamic acid benzyl ester

Guidance literature:: Multi-step reaction with 7 steps

1: 35 percent / glacial acetic acid / 1.) 22 deg C, 1 h; 2.) 85 deg C, 1.5 h

2: N-methylmorpholine oxide dihydrate, osmium tetroxide / tetrahydrofuran; H₂O / 22 °C

3: 81 percent / 2N NaOH / H₂O / 25 °C

4: dicyclohexylcarbodiimide, pyridine / CH₂Cl₂

5: methanol

6: 89 percent / O₂ / 10percent Pt/C / H₂O / 36 h / 50 °C

7: oxalyl chloride, dimethylformamide / CH₂Cl₂ / 1.) 30 min., 0 deg C; 2.) 45 min., r.t.

With pyridine; sodium hydroxide; osmium(VIII) oxide; oxalyl dichloride; oxygen; acetic acid; 4-methylmorpholine N-oxide; N,N-dimethyl-formamide; dicyclohexyl-carbodiimide; platinum on activated charcoal; In tetrahydrofuran; methanol; dichloromethane; water;

Reference yield:

: 621-84-1
O-benzyl carbamate

: 111603-41-9
(6-Chlorocarbonyl-2-methoxy-2-oxo-2λ⁵-[1,2]oxaphosphinan-3-yl)-carbamic acid benzyl ester

Guidance literature:: Multi-step reaction with 7 steps

1: 35 percent / glacial acetic acid / 1.) 22 deg C, 1 h; 2.) 85 deg C, 1.5 h

2: N-methylmorpholine oxide dihydrate, osmium tetroxide / tetrahydrofuran; H₂O / 22 °C

3: 81 percent / 2N NaOH / H₂O / 25 °C

4: dicyclohexylcarbodiimide, pyridine / CH₂Cl₂

5: methanol

6: 89 percent / O₂ / 10percent Pt/C / H₂O / 36 h / 50 °C

7: oxalyl chloride, dimethylformamide / CH₂Cl₂ / 1.) 30 min., 0 deg C; 2.) 45 min., r.t.

With pyridine; sodium hydroxide; osmium(VIII) oxide; oxalyl dichloride; oxygen; acetic acid; 4-methylmorpholine N-oxide; N,N-dimethyl-formamide; dicyclohexyl-carbodiimide; platinum on activated charcoal; In tetrahydrofuran; methanol; dichloromethane; water;

Reference yield:

: (2-Hydroxy-6-hydroxymethyl-2-oxo-2λ⁵-[1,2]oxaphosphinan-3-yl)-carbamic acid benzyl ester

: 111603-41-9
(6-Chlorocarbonyl-2-methoxy-2-oxo-2λ⁵-[1,2]oxaphosphinan-3-yl)-carbamic acid benzyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: methanol

2: 89 percent / O₂ / 10percent Pt/C / H₂O / 36 h / 50 °C

3: oxalyl chloride, dimethylformamide / CH₂Cl₂ / 1.) 30 min., 0 deg C; 2.) 45 min., r.t.

With oxalyl dichloride; oxygen; N,N-dimethyl-formamide; platinum on activated charcoal; In methanol; dichloromethane; water;