2-Propenoic acid, 2-[methyl[(tridecafluorohexyl)sulfonyl]amino]ethyl ester

Base Information

• Chemical Name: 2-Propenoic acid, 2-[methyl[(tridecafluorohexyl)sulfonyl]amino]ethyl ester
• CAS No.: 67584-57-0
• Deprecated CAS: 157122-25-3
• Molecular Formula: C₁₂H₁₀F₁₃NO₄S
• Molecular Weight: 511.261
• European Community (EC) Number: 266-735-6
• DSSTox Substance ID: DTXSID7070509
• Nikkaji Number: J310.276I
• Wikidata: Q81997836
• Mol file: 67584-57-0.mol

Synonyms:67584-57-0;2-Propenoic acid, 2-[methyl[(tridecafluorohexyl)sulfonyl]amino]ethyl ester;2-[methyl(1,1,2,2,3,3,4,4,5,5,6,6,6-tridecafluorohexylsulfonyl)amino]ethyl prop-2-enoate;EINECS 266-735-6;ACRYLIC ACID 2-[METHYL[(TRIDECAFLUOROHEXYL)SULFONYL]AMINO]ETHYL ESTER;2-(Methyl((tridecafluorohexyl)sulphonyl)amino)ethyl acrylate;2-Propenoic acid 2-(((tridecafluorohexyl)sulfonyl)methylamino)ethyl ester;2-Propenoic acid, 2-(methyl((tridecafluorohexyl)sulfonyl)amino)ethyl ester;2-Propenoic acid, 2-(methyl((1,1,2,2,3,3,4,4,5,5,6,6,6-tridecafluorohexyl)sulfonyl)amino)ethyl ester;2-[METHYL[(TRIDECAFLUOROHEXYL)SULPHONYL]AMINO]ETHYL ACRYLATE;C12H10F13NO4S;DTXSID7070509;SCHEMBL16178607;2-Propenoic acid 2-(((tridecafluorohexyl)sulfonyl)methylamino)ethylester;C12-H10-F13-N-O4-S;FT-0774640;(N-methylperfluorohexylsulfonamido)ethyl acrylate;[N-Methylperfluorohexane-1-sulfonamide]ethyl acrylate;Acrylic acid 2-[methyl(tridecafluorohexylsulfonyl)amino]ethyl ester;2-(N-methyl1,1,2,2,3,3,4,4,5,5,6,6,6- tridecafluorohexanesulfonamido)ethyl prop-2-enoate

Chemical Property of 2-Propenoic acid, 2-[methyl[(tridecafluorohexyl)sulfonyl]amino]ethyl ester

Chemical Property:

• Vapor Pressure: 0.00025mmHg at 25°C
• Boiling Point: 324.2°C at 760 mmHg
• PKA: -9.47±0.70(Predicted)
• Flash Point: 149.9°C
• PSA: 72.06000
• Density: 1.575g/cm³
• LogP: 4.75430
• XLogP3: 4.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 18
• Rotatable Bond Count: 11
• Exact Mass: 511.0122951
• Heavy Atom Count: 31
• Complexity: 785

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CN(CCOC(=O)C=C)S(=O)(=O)C(C(C(C(C(C(F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F

Technology Process of 2-Propenoic acid, 2-[methyl[(tridecafluorohexyl)sulfonyl]amino]ethyl ester

There total 2 articles about 2-Propenoic acid, 2-[methyl[(tridecafluorohexyl)sulfonyl]amino]ethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.5%

N-hydroxyethyl-N-methylperfluorohexylsulfonamide (68555-75-9) + acrylic acid methyl ester (292638-85-8,9003-21-8,96-33-3) → (N-methylperfluorohexylsulfonamido)ethyl acrylate (67584-57-0)

Guidance literature:

With sodium methylate; at 74 - 76 ℃; for 10h; Large scale;

Reference yield:

tridecafluorohexanesulfonyl fluoride (423-50-7) → (N-methylperfluorohexylsulfonamido)ethyl acrylate (67584-57-0)

Guidance literature:

Multi-step reaction with 3 steps

1: sodium chloride / water / 12 h / -8 - 50 °C

2: sodium carbonate / n-heptane / 11 h / 105 - 110 °C

3: sodium methylate / 10 h / 74 - 76 °C / Large scale

With sodium methylate; sodium carbonate; sodium chloride; In n-heptane; water;

upstream raw materials:

N-hydroxyethyl-N-methylperfluorohexylsulfonamide

acrylic acid methyl ester

tridecafluorohexanesulfonyl fluoride

Refernces