2-(CHLOROMETHYL)ANTHRAQUINONE

Base Information

• Chemical Name: 2-(CHLOROMETHYL)ANTHRAQUINONE
• CAS No.: 6374-87-4
• Molecular Formula: C15H9 Cl O2
• Molecular Weight: 256.688
• Hs Code.: 2914700090
• Mol file: 6374-87-4.mol

Synonyms:Anthraquinone,2-(chloromethyl)- (6CI,7CI,8CI); 2-(Chloromethyl)-9,10-anthraquinone;2-(Chloromethyl)anthraquinone; NSC 401159

Chemical Property of 2-(CHLOROMETHYL)ANTHRAQUINONE

Chemical Property:

• Vapor Pressure: 1.4E-08mmHg at 25°C
• Melting Point: 166-169 °C(lit.)
• Boiling Point: 458.2°C at 760 mmHg
• Flash Point: 192.9°C
• PSA: 34.14000
• Density: 1.374g/cm³
• LogP: 3.20080

Purity/Quality:

98%,99%, ^*data from raw suppliers

2-(Chloromethyl)anthraquinone 98% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): 1975355
• Hazard Codes: C
• Statements: 34
• Safety Statements: 26-36/37/39-45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Uses: 2-(Chloromethyl)anthraquinone may be used in the following processes: Synthesis of 2-[methylamino-N-(1′-methyl-4′-N,N-diethylaminobutyl)]anthraquinone diphosphate. Synthesis of 2-(3,4-dicyano-phenyl)-2-(9,10-dioxo-9,10-dihydroantracen-2-yl-methyl)-malonic acid diethyl ester, starting reagent for the synthesis of tetra substituted metallophthalocyanines.To alter the glassy carbon (GC) electrode surface in order to investigate the oxygen reduction reaction (ORR) in alkaline medium.

Technology Process of 2-(CHLOROMETHYL)ANTHRAQUINONE

There total 5 articles about 2-(CHLOROMETHYL)ANTHRAQUINONE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

2-methylanthracene-9,10-dione (84-54-8) → 2-(chloromethyl)anthracene-9,10-dione (6374-87-4)

Guidance literature:

With sulfuryl dichloride; 2,2'-azobis(isobutyronitrile); for 1h; Heating;

DOI:10.1021/jm00185a019

Reference yield:

2-methylanthracene-9,10-dione (84-54-8) + chlorine (7782-50-5) + nitrobenzene (98-95-3,26969-40-4) → 2-(chloromethyl)anthracene-9,10-dione (6374-87-4) + anthraquinone-2-carboxylic acid (117-78-2)

Guidance literature:

Sonnenlicht;

Reference yield:

2-methylanthracene-9,10-dione (84-54-8) → 2-(chloromethyl)anthracene-9,10-dione (6374-87-4) + 2-dichloromethyl-anthraquinone (93986-56-2)

Guidance literature:

With sulfuryl dichloride; benzene; dibenzoyl peroxide;

upstream raw materials:

2-methylanthracene-9,10-dione

chlorine

nitrobenzene

sulfuryl dichloride

Downstream raw materials:

2-p-toluenesulfonylmethylanthraquinone

2-methylanthracene-9,10-dione

2-isopropylidenemethylanthraquinone

2-(2-methyl 2-nitropropyl)anthraquinone

Refernces

• 1、 Crozet, Michel P.,Jentzer, Olivier,Vanelle, Patrice. "REACTIONS DE SUBSTITUTION SRN1 EN SERIE QUINONIQUE". . p. 5531 - 5534. Retrieved 2007/10/02.