Sulfamic acid, diethyl-, 2-[(4-nitrophenyl)thio]cyclohexyl ester, trans-

Base Information

• Chemical Name: Sulfamic acid, diethyl-, 2-[(4-nitrophenyl)thio]cyclohexyl ester, trans-
• CAS No.: 112128-62-8
• Molecular Formula: C₁₆H₂₄N₂O₅S₂
• Molecular Weight: 388.509
• Mol file: 112128-62-8.mol

Synonyms:

Chemical Property of Sulfamic acid, diethyl-, 2-[(4-nitrophenyl)thio]cyclohexyl ester, trans-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Sulfamic acid, diethyl-, 2-[(4-nitrophenyl)thio]cyclohexyl ester, trans-

There total 2 articles about Sulfamic acid, diethyl-, 2-[(4-nitrophenyl)thio]cyclohexyl ester, trans- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.5%

N,N-Diethyl-S-(4-nitro-phenyl)-thiohydroxylamine (112128-60-6) + cyclohexene (110-83-8) → trans-2-(4-nitrophenylthio)cyclohexyl N,N-diethylsulfamate (112128-62-8)

Guidance literature:

With sulfur trioxide; In dichloromethane; at -85 ℃; for 1h; Mechanism; 1.) -85 deg C, 1 hr., 2.) warming up to r.t.;

Reference yield:

C10H14N2O5S2 + cyclohexene (110-83-8) → trans-2-(4-nitrophenylthio)cyclohexan-1-ol (112128-61-7) + trans-2-(4-nitrophenylthio)cyclohexyl N,N-diethylsulfamate (112128-62-8)

Guidance literature:

In dichloromethane; Yield given. Yields of byproduct given; 1.) -85 deg C, 1 hr, 2.) slow heating up to r.t.;

Reference yield:

trans-2-(4-nitrophenylthio)cyclohexyl N,N-diethylsulfamate (112128-62-8) → trans-2-(4-nitrophenylthio)cyclohexan-1-ol (112128-61-7)

Guidance literature:

With water;

upstream raw materials:

cyclohexene

N,N-Diethyl-S-(4-nitro-phenyl)-thiohydroxylamine

Downstream raw materials:

trans-2-(4-nitrophenylthio)cyclohexan-1-ol

trans-2-acetoxycyclohexyl 4-nitronitrophenyl sulphide