2-Azido-5-bromobenzoyl chloride

Base Information

Chemical Name:2-Azido-5-bromobenzoyl chloride
CAS No.:112253-71-1
Molecular Formula:C7H3BrClN3O
Molecular Weight:260.477
Hs Code.:
DSSTox Substance ID:DTXSID901304272

Synonyms:2-Azido-5-bromobenzoyl chloride;DTXSID901304272;112253-71-1

Suppliers and Price of 2-Azido-5-bromobenzoyl chloride

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 2-Azido-5-bromobenzoyl chloride

Chemical Property:

XLogP3:4.1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:2
Exact Mass:258.91480
Heavy Atom Count:13
Complexity:254

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C1=CC(=C(C=C1Br)C(=O)Cl)N=[N+]=[N-]

Technology Process of 2-Azido-5-bromobenzoyl chloride

There total 4 articles about 2-Azido-5-bromobenzoyl chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 112253-72-2
2-azido-5-bromobenzoic acid

: 112253-71-1
2-azido-5-bromobenzoyl chloride

Guidance literature:: With thionyl chloride;

Reference yield:

: 1001621-59-5
2-azido-5-bromobenzaldehyde

: 112253-71-1
2-azido-5-bromobenzoyl chloride

Guidance literature:: Multi-step reaction with 2 steps

1: 2-methyl-but-2-ene; sodium chlorite; sodium dihydrogenphosphate / tetrahydrofuran; tert-butyl alcohol; water / 0 - 20 °C

2: oxalyl dichloride; N,N-dimethyl-formamide / dichloromethane / 3.25 h / 0 - 20 °C

With sodium chlorite; sodium dihydrogenphosphate; 2-methyl-but-2-ene; oxalyl dichloride; N,N-dimethyl-formamide; In tetrahydrofuran; dichloromethane; water; tert-butyl alcohol;
DOI:10.1016/j.tetlet.2021.152828

Reference yield:

: 93777-26-5
5-bromo-2-fluorobenzaldehyde

: 112253-71-1
2-azido-5-bromobenzoyl chloride

Guidance literature:: Multi-step reaction with 3 steps

1: sodium azide / dimethyl sulfoxide / 50 °C

2: 2-methyl-but-2-ene; sodium chlorite; sodium dihydrogenphosphate / tetrahydrofuran; tert-butyl alcohol; water / 0 - 20 °C

3: oxalyl dichloride; N,N-dimethyl-formamide / dichloromethane / 3.25 h / 0 - 20 °C

With sodium chlorite; sodium dihydrogenphosphate; sodium azide; 2-methyl-but-2-ene; oxalyl dichloride; N,N-dimethyl-formamide; In tetrahydrofuran; dichloromethane; water; dimethyl sulfoxide; tert-butyl alcohol;
DOI:10.1016/j.tetlet.2021.152828