Phosphonium, (2-carboxy-2-((methoxycarbonyl)amino)ethyl)triphenyl-, (S)-

Base Information

Chemical Name:Phosphonium, (2-carboxy-2-((methoxycarbonyl)amino)ethyl)triphenyl-, (S)-
CAS No.:96854-29-4
Molecular Formula:C₂₃H₂₃NO₄P*Cl
Molecular Weight:443.867
Hs Code.:
Mol file:96854-29-4.mol

Synonyms:(2-carboxy-2-((methoxycarbonyl)amino)ethyl)triphenylphosphonium;(2-carboxy-2-((methoxycarbonyl)amino)ethyl)triphenylphosphonium chloride;2-CMETP

Suppliers and Price of Phosphonium, (2-carboxy-2-((methoxycarbonyl)amino)ethyl)triphenyl-, (S)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 2 raw suppliers

Chemical Property of Phosphonium, (2-carboxy-2-((methoxycarbonyl)amino)ethyl)triphenyl-, (S)-

Chemical Property:

Boiling Point:°Cat760mmHg
Flash Point:°C
Density:g/cm³
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:5
Rotatable Bond Count:8
Exact Mass:443.1053229
Heavy Atom Count:30
Complexity:491

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:COC(=O)NC(C[P+](C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3)C(=O)O.[Cl-]
Isomeric SMILES:COC(=O)N[C@H](C[P+](C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3)C(=O)O.[Cl-]

Technology Process of Phosphonium, (2-carboxy-2-((methoxycarbonyl)amino)ethyl)triphenyl-, (S)-

There total 6 articles about Phosphonium, (2-carboxy-2-((methoxycarbonyl)amino)ethyl)triphenyl-, (S)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 99259-18-4
(R)-3-Iodo-2-<(methoxycarbonyl)amino>propanoic Acid Benzyl Ester

: 148469-28-7,96854-29-4
(R)-<2-Carboxy-2-<(methoxycarbonyl)amino>ethyl>triphenylphosphonium Chloride

Guidance literature:: Multi-step reaction with 3 steps

1: toluene / 816 h / 50 °C

2: Amberlyst A-26

3: H₂ / Pd-C

With Amberlyst A-26; hydrogen; palladium on activated charcoal; In toluene;
DOI:10.1016/S0040-4039(01)80814-5

Reference yield:

: 603-35-0
triphenylphosphine

: 148469-28-7,96854-29-4
(R)-<2-Carboxy-2-<(methoxycarbonyl)amino>ethyl>triphenylphosphonium Chloride

Guidance literature:: Multi-step reaction with 3 steps

1: toluene / 816 h / 50 °C

2: Amberlyst A-26

3: H₂ / Pd-C

With Amberlyst A-26; hydrogen; palladium on activated charcoal; In toluene;
DOI:10.1016/S0040-4039(01)80814-5

Reference yield:

: 99259-17-3
(S)-N-(Methoxycarbonyl)serine Benzyl Ester

: 148469-28-7,96854-29-4
(R)-<2-Carboxy-2-<(methoxycarbonyl)amino>ethyl>triphenylphosphonium Chloride

Guidance literature:: Multi-step reaction with 4 steps

1: 65 percent / pyridine / 3 h / -10 °C

2: 100 percent / NaI / acetone / 72 h / Ambient temperature

3: 97 percent / toluene / 120 h / 50 °C

4: 1.) Amberlyst A-26 (Cl^-), 2.) hydrogen / 2.) 10percent Pd/C / 1.) aq. EtOH; 2.) EtOH, 1 atm, 21 h

With pyridine; Amberlyst A-26 (Cl^-); hydrogen; sodium iodide; palladium on activated charcoal; In acetone; toluene;
DOI:10.1248/cpb.39.1407