Benzenepentanethioic acid, b-methylene-, S-ethyl ester

Base Information

• Chemical Name: Benzenepentanethioic acid, b-methylene-, S-ethyl ester
• CAS No.: 112303-80-7
• Molecular Formula: C₁₄H₁₈OS
• Molecular Weight: 234.362
• Mol file: 112303-80-7.mol

Synonyms:

Chemical Property of Benzenepentanethioic acid, b-methylene-, S-ethyl ester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Benzenepentanethioic acid, b-methylene-, S-ethyl ester

There total 2 articles about Benzenepentanethioic acid, b-methylene-, S-ethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-(Et-thio)carbonyl-2-phenethylpropyl cobaloxime → 2-(Et-thio)carbonyl2-phenethylpropane (112303-76-1) + 3-Methylene-5-phenyl-pentanethioic acid S-ethyl ester (112303-80-7) + 2-Methyl-1,2,3,4-tetrahydro-naphthalene-2-carbothioic acid S-ethyl ester (112303-83-0)

Guidance literature:

In chloroform; Irradiation (UV/VIS); irradiation of soln. of Co-compd. by a high pressure mercury lamp (400 W); chromy. on silica gel (CHCl3), sepn. by TLC, total yield 80-90 %, ratio phenethylpropane/tetraline = 75:25;

DOI:10.1246/cl.1987.409

Reference yield:

→ 2-(Et-thio)carbonyl2-phenethylpropane (112303-76-1) + 3-Methylene-5-phenyl-pentanethioic acid S-ethyl ester (112303-80-7) + 2-Methyl-1,2,3,4-tetrahydro-naphthalene-2-carbothioic acid S-ethyl ester (112303-83-0)

Guidance literature:

In methanol; Irradiation;

DOI:10.1246/cl.1987.409