Agn-PC-00efma

Base Information

Chemical Name:Agn-PC-00efma
CAS No.:17460-38-7
Molecular Formula:C14H17 N3 O5
Molecular Weight:307.306
Hs Code.:
NSC Number:212138,125616
DSSTox Substance ID:DTXSID90400575,DTXSID60942538

Synonyms:20379-52-6;17460-38-7;AGN-PC-00EFMA;SCHEMBL14864298;DTXSID60942538;DTXSID90400575;NSC125616;NSC212138;NSC-125616;NSC-212138;Methyl 3-azido-4,6-O-benzylidene-3-deoxyhexopyranoside

Suppliers and Price of Agn-PC-00efma

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 6 raw suppliers

Chemical Property of Agn-PC-00efma

Chemical Property:

Boiling Point:°Cat760mmHg
Flash Point:°C
Density:g/cm³
XLogP3:1.4
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:7
Rotatable Bond Count:3
Exact Mass:307.11682065
Heavy Atom Count:22
Complexity:425

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC1C(C(C2C(O1)COC(O2)C3=CC=CC=C3)N=[N+]=[N-])O

Technology Process of Agn-PC-00efma

There total 1 articles about Agn-PC-00efma which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 17460-38-7
methyl 3-azido-4,6-O-benzylidene-3-deoxy-α-D-altropyranoside

Guidance literature:: Methyl-2-O-p-toluolsulfonyl-4,6-O-benzyliden-α-D-glucosid, wss. Natriumazid <2-Methoxy-aethanol, Siedetemp., 24 Std.>;
DOI:10.1039/jr9630005288

Reference yield: 91.6%

: 17460-38-7
methyl 3-azido-4,6-O-benzylidene-3-deoxy-α-D-altropyranoside

: 358-23-6
trifluoromethylsulfonic anhydride

: methyl 3-azido-4,6-O-benzylidene-3-deoxy-2-O-trifluoromethanesulphonyl-α-D-altropyranoside

Guidance literature:: With pyridine; In dichloromethane; 1.) -15 deg C, 10 min; 2.) 0 deg C, 40 min;
DOI:10.1016/0008-6215(88)80013-2

Reference yield:

: 17460-38-7
methyl 3-azido-4,6-O-benzylidene-3-deoxy-α-D-altropyranoside

: 72741-87-8,96648-51-0,96648-52-1,102208-67-3,107982-28-5,111467-60-8,113299-92-6,116497-15-5,148261-04-5,116497-16-6
(1S,2R,8S,8aS)-octahydro-1,2,8-indolizidinetriol

Guidance literature:: Multi-step reaction with 17 steps

1: 1.) NaH / 1.) DMF, 0 deg C, 5 min, 2.) RT, 1 h

2: 80percent aq. acetic acid / 4 h / 100 °C

3: concd. H₂SO₄ / 4 h / Ambient temperature

4: 82 percent / sodium methoxide / methanol / 0.08 h / Ambient temperature

5: 64 percent / pyridine, triethylamine / 6 h / Ambient temperature

6: 60 percent / benzene / 3 h / Heating

7: 88 percent / camphorsulfonic acid / acetone / 2 h / Ambient temperature

8: H₂ / Raney nickel W-4 / ethanol / 36 h / 760 Torr / Ambient temperature

9: Bu₄NF / tetrahydrofuran / 4 h / Ambient temperature

10: pyridine / 3 h / 40 °C

11: K₂CO₃ / dioxane; H₂O / 2 h / 90 °C

12: 64 percent / cyclohexene, 20percent Pd(OH)2/C / ethanol / 26 h / Heating

13: 83 percent / pyridine / 4 h / Ambient temperature

14: 84 percent / dimethylformamide / 0.5 h / 140 °C

15: BH₃-Me₂S / tetrahydrofuran / 2 h / Ambient temperature

16: K₂CO₃ / methanol / 2 h / 65 °C

17: 84 percent / 1 M aq. HCl / 0.5 h / Heating

With pyridine; hydrogenchloride; palladium dihydroxide; dimethylsulfide borane complex; sulfuric acid; camphor-10-sulfonic acid; tetrabutyl ammonium fluoride; hydrogen; sodium methylate; sodium hydride; potassium carbonate; acetic acid; triethylamine; cyclohexene; Raney nickel W-4; In tetrahydrofuran; 1,4-dioxane; methanol; ethanol; water; N,N-dimethyl-formamide; acetone; benzene;
DOI:10.1021/jo00257a003