1-Phenyl-4,5,6,7-tetrahydro-1h-benzotriazole

Base Information

Chemical Name:1-Phenyl-4,5,6,7-tetrahydro-1h-benzotriazole
CAS No.:32987-10-3
Molecular Formula:C12H13N3
Molecular Weight:199.2517
Hs Code.:
NSC Number:133509
DSSTox Substance ID:DTXSID90299885
Nikkaji Number:J2.744.961A
Wikidata:Q82042579

Synonyms:1-phenyl-4,5,6,7-tetrahydro-1h-benzotriazole;32987-10-3;1-phenyl-4,5,6,7-tetrahydro-1H-benzo[d][1,2,3]triazole;NSC133509;DTXSID90299885;NSC-133509

Suppliers and Price of 1-Phenyl-4,5,6,7-tetrahydro-1h-benzotriazole

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 5 raw suppliers

Chemical Property of 1-Phenyl-4,5,6,7-tetrahydro-1h-benzotriazole

Chemical Property:

Vapor Pressure:8.76E-06mmHg at 25°C
Boiling Point:373.8°Cat760mmHg
Flash Point:179.8°C
Density:1.24g/cm³
XLogP3:2.4
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:1
Exact Mass:199.110947427
Heavy Atom Count:15
Complexity:213

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1CCC2=C(C1)N=NN2C3=CC=CC=C3

Technology Process of 1-Phenyl-4,5,6,7-tetrahydro-1h-benzotriazole

There total 7 articles about 1-Phenyl-4,5,6,7-tetrahydro-1h-benzotriazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 108-94-1,11119-77-0,9003-41-2,9075-99-4
cyclohexanone

: 622-37-7
Phenyl azide

: 32987-10-3
1-phenyl-4,5,6,7-tetrahydro-1H-benzo[d][1,2,3]triazole

Guidance literature:: With L-proline; In dichloromethane; at 80 ℃; for 1h; Sealed tube; Microwave irradiation;
DOI:10.1002/chem.201102046

Reference yield: 84.0%

: 878191-46-9
1,2,5,6-tetraaza-dispiro[2.0.2.4]deca-1,5-diene

: 622-37-7
Phenyl azide

: 32987-10-3
1-phenyl-4,5,6,7-tetrahydro-1H-benzo[d][1,2,3]triazole

Guidance literature:: In chloroform-d1; at 40 - 60 ℃; for 4h;
DOI:10.1002/anie.200503124

Reference yield:

: 878191-43-6
1,2,5,6-tetraaza-dispiro[2.0.2.4]decane

: 32987-10-3
1-phenyl-4,5,6,7-tetrahydro-1H-benzo[d][1,2,3]triazole

Guidance literature:: Multi-step reaction with 2 steps

1: 67 percent / AgNO₃; sodium hydroxide / CHCl₃ / 5 h / cooling

2: 84 percent / CDCl₃ / 4 h / 40 - 60 °C

With sodium hydroxide; silver nitrate; In chloroform-d1; chloroform;
DOI:10.1002/anie.200503124