Technology Process of 2,2,2-Trifluoro-1,1-diphenylethanesulfinyl chloride
There total 5 articles about 2,2,2-Trifluoro-1,1-diphenylethanesulfinyl chloride which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
trifluoroacetyl peroxide;
In
dichloromethane;
0 deg C, 1 h; room temp., 1 h;
DOI:10.1055/s-1987-28045
- Guidance literature:
-
Multi-step reaction with 5 steps
1: 1.) Mg / 1.) ether, 2.) reflux, 1 h
2: 1.) NaH / 1.) ether, room temp., 1 h, 2.) room temp., 70 h
3: 96 percent / H2S, p-TsOH / various solvent(s) / 1 h / 60 °C
4: 96 percent / sulfuryl chloride / diethyl ether / 0.25 h / Ambient temperature
5: 100 percent / CF3CO3H / CH2Cl2 / 0 deg C, 1 h; room temp., 1 h
With
sulfuryl dichloride; trifluoroacetyl peroxide; hydrogen sulfide; sodium hydride; toluene-4-sulfonic acid; magnesium;
In
diethyl ether; dichloromethane;
DOI:10.1055/s-1987-28045
- Guidance literature:
-
Multi-step reaction with 4 steps
1: 1.) NaH / 1.) ether, room temp., 1 h, 2.) room temp., 70 h
2: 96 percent / H2S, p-TsOH / various solvent(s) / 1 h / 60 °C
3: 96 percent / sulfuryl chloride / diethyl ether / 0.25 h / Ambient temperature
4: 100 percent / CF3CO3H / CH2Cl2 / 0 deg C, 1 h; room temp., 1 h
With
sulfuryl dichloride; trifluoroacetyl peroxide; hydrogen sulfide; sodium hydride; toluene-4-sulfonic acid;
In
diethyl ether; dichloromethane;
DOI:10.1055/s-1987-28045
